Synthesis and Crystal Structure of Bis{2-[(2-hydroxymethylphenyl)-iminomethyl]phenolato}chromium(III) nitrate monohydrate

Koikawa, Masayuki; Toyofuku, Takashi; Muto, Masahiro; Yamada, Yasunori; Tokii, Tadashi

doi:10.2116/xraystruct.28.33

Cited by 3 publications

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“…The complex has a same meridional octahedral coordination as the previously reported mononuclear complexes with H2L1-H ligand. 7,8 The equatorial plane is defined by four oxygen donors, and the axial positions are occupied by two nitrogen donors. The Ni1-O1 and Ni1-O5 distances [2.0990(15) and 2.0728(15)Å], involving protonated O atoms, are ca.…”

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Synthesis and Crystal Structure of Bis{2-[(2-hydroxymethylphenyl)iminomethyl]-4-nitrophenolato}nickel(II) Monoacetonitrile

MINEYAMA

Yoneda

Yamada

et al. 2021

X-ray Structure Analysis Online

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The title compound, [Ni(HL1-NO2)2]•CH3CN, [H2L1-NO2 = 2-[2-(hydroxymethylphenyl)iminomethyl]-4-nitrophenol], was synthesized and characterized by single-crystal X-ray analysis. The compound crystallizes in the triclinic space group P1 with cell parameters a = 10.556(2)Å, b = 11.779(3)Å, c = 12.247(3)Å, α = 86.412(10)°, β = 71.135(8)°, γ = 73.009( 8)°, V = 1377.2(5)Å 3 , Dcalcd = 1.549 g/cm 3 , Z = 2. The R1 [I > 2σ(I)] and wR2 (all data) values are 0.0362 and 0.1024, respectively, for all 5989 independent reflections. The tridentate ligands coordinate to the nickel atom as a mermanner.

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confidence: 99%