Synthesis and crystal structure of a one-dimensional coordination polymer of nickel(II) with 4′-(imidazol-1-ylmethyl)benzoate anion

Fan, Jian; Zhang, Yanan; Okamura, Taka‐aki; Zou, Zhi-Hong; Ueyama, Norikazu; Sun, Wei‐Yin

doi:10.1016/s1387-7003(01)00259-3

Cited by 18 publications

(4 citation statements)

References 13 publications

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“…The CSD Refcodes presenting in each type of topology are listed below: CICZUJ[64]OGALEO[71]FEGGAA[78]MEFZUS[87]VIKCOI[97]CEYLOI[104]PIFBAI[65]OGALIS[71]FOHFUE[79]MENGAO[88]VIQYEA[98]ECULUK[105]PODZOY[66]OKEHIV[72]GOYSES[80]NENDAL[89]VIQYIE[98]OKEHIV01[67]AVUPUC[67]OKEHOB[72]GOYSIW[80]NIQGUQ[90]WUPHEU[99]RAJNOG[106]AVUQOX[67]VOBKUT[73]HIHJIS[81]PAJJOA[91]XIBPAA[100]KOBGUE[40]DOGMAO[68]

…”

Section: One-dimensional Coordination Chainsmentioning

confidence: 99%

Supramolecular Coordination Assemblies Constructed From Multifunctional Azole-Containing Carboxylic Acids

Deng

Líu

et al. 2010

Molecules

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This paper provides a brief review of recent progress in the field of metal coordination polymers assembled from azole-containing carboxylic acids and gives a diagrammatic summary of the diversity of topological structures in the resulting infinite metal-organic coordination networks (MOCNs). Azole-containing carboxylic acids are a favorable kind of multifunctional ligand to construct various metal complexes with isolated complexes and one, two and three dimensional structures, whose isolated complexes are not the focus of this review. An insight into the topology patterns of the infinite coordination polymers is provided. Analyzed topologies are compared with documented topologies and catalogued by the nature of nodes and connectivity pattern. New topologies which are not available from current topology databases are described and demonstrated graphically.

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…”

Section: One-dimensional Coordination Chainsmentioning

confidence: 99%

Supramolecular Coordination Assemblies Constructed From Multifunctional Azole-Containing Carboxylic Acids

Deng

Líu

et al. 2010

Molecules

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“…The ligands used, denoted as L1, L2, L3 and L4 are outlined in Scheme (I) [1,3-bis(imidazol-1-ylmethyl)benzene (L1), 1,3-bis(imidazol-1-ylmethyl)-5-methylbenzene (L2), 1,3bis(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene (L3), 1,3bis(2-methylimidazol-1-ylmethyl)-2,4,6-trimethylbenzene (L4)]. L1, L2 and L3 have previously been employed by our group and other researchers in the formation of metal complexes involving various 3d-block metal ions, such as Cd II , Cu II , Zn II , Ag II , Ni II and Co II (Arhangelskis et al, 2021;Liu et al, 2021;Alen et al, 2015;Bisht et al, 2014a,b;Dobrzan ´ska et al, 2006;Zhang et al, 2014;Ma et al, 2013;Dobrzan ´ska, 2011;Strasser et al, 2010;Liu et al, 2009;Mukherjee et al, 2008;Liu, Hu et al, 2001;Liu, Su et al, 2001;Sun et al, 2000;Yang et al, 2013;Yao et al, 2008;Sui et al, 2005Sui et al, , 2001Ma et al, 2003;Fan et al, 2001). On the other hand, L4 is novel and used for the first time in this study.…”

Section: Introductionmentioning

confidence: 99%

Tailoring the dimensionality of metal complexes via ligand modifications

Le Garff,

Maria Losus,

Chaudhary

et al. 2024

Acta Crystallogr Sect B

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A series of CuII complexes obtained under the same reaction conditions has been analyzed to gain insight into the effect of the ligand composition on the final reaction product. Dipodal ligands containing N-donor imidazole rings and a benzene ring as a spacer with different numbers of methyl substituents on the aromatic rings were selected for the study such as 1,3-bis(imidazol-1-ylmethyl)benzene (L1), 1,3-bis(imidazol-1-ylmethyl)-5-methylbenzene (L2), 1,3-bis(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene (L3), 1,3-bis(2-methylimidazol-1-ylmethyl)-2,4,6-trimethylbenzene (L4). L4 has not been reported previously and was synthesized for this study. The formed metal complexes show the presence of polymeric (ligand with no or one methyl substituent; 1–4), or discrete motifs (3- or 5-methyl substituents; 5–7). The new metal complexes 3, 5 and 6 were analyzed using single-crystal X-ray diffraction and powder diffraction. In addition, the structural analyses were supported by computational methods.

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“…Enhancing N719 absorption efficiency in the full-spectrum of sunlight still remains a great challenge in this field. [11][12][13][14][15] The enormous variability of available ligandmetal combinations opens the possibility of creating photovoltaic materials "by design". The key to the design of photoelectric MCCs is the matching of an organic ligand and a central metal ion in order to provide the platform to generate ultraviolet absorption.…”

Section: Introductionmentioning

confidence: 99%

“…9,10 Among the organic ligands, the rigid ligand 4-(1H-imidazol-1-yl)benzoic acid with a π-conjugated system plays crucial roles in determining the structure and ultraviolet absorption of the MCCs because of the diversiform coordination mode and the flexible nature of N and/or O donors. [11][12][13][14][15] The enormous variability of available ligandmetal combinations opens the possibility of creating photovoltaic materials "by design". Cd II has been chosen as an excellent participant for the construction of complexes because of its relatively low-cost (compared to Ir III , Ru II , Os II and Pt II , which are used as common co-sensitizers).…”

Section: Introductionmentioning

confidence: 99%

Advanced Cd^II complexes as high efficiency co-sensitizers for enhanced dye-sensitized solar cell performance

et al. 2015

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This work reports on two new complexes with the general formula [Cd3(IBA)3(Cl)2(HCOO)(H2O)]n (1) and {[Cd1.5(IBA)3(H2O)6]·3.5H2O}n (2), which can be synthesized by the reaction of Cd(II) with rigid linear ligand 4-HIBA containing imidazolyl and carboxylate functional groups [4-HIBA = 4-(1H-imidazol-1-yl)benzoic acid]. Single-crystal X-ray diffraction analyses indicate that complex 1 is a 2D "wave-like" layer structure constructed from trinuclear units and complex 2 is just a mononuclear structure. Surprisingly, both complexes 1 and 2 appear as a 3D supramolecular network via intermolecular hydrogen bonding interactions. What's more, due to their strong UV-visible absorption, 1 and 2 can be employed as co-sensitizers in combination with N719 to enhance dye-sensitized solar cell (DSSC) performance. Both of them could overcome the deficiency of the ruthenium complex N719 absorption in the region of ultraviolet and blue-violet, and the charge collection efficiency is also improved when 1 and 2 are used as co-sensitizers, which are all in favor of enhancing the performance. The DSSC devices using co-sensitizers of 1/N719 and 2/N719 show an overall conversion efficiency of 8.27% and 7.73% with a short circuit current density of 17.48 mA cm(-2) and 17.39 mA cm(-2), and an open circuit voltage of 0.75 V and 0.74 V, respectively. The overall conversion efficiency is 27.23% and 18.92% higher than that of a device solely sensitized by N719 (6.50%). Consequently, the prepared complexes are high efficiency co-sensitizers for enhancing the performance of N719 sensitized solar cells.

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Synthesis and crystal structure of a one-dimensional coordination polymer of nickel(II) with 4′-(imidazol-1-ylmethyl)benzoate anion

Cited by 18 publications

References 13 publications

Supramolecular Coordination Assemblies Constructed From Multifunctional Azole-Containing Carboxylic Acids

Supramolecular Coordination Assemblies Constructed From Multifunctional Azole-Containing Carboxylic Acids

Tailoring the dimensionality of metal complexes via ligand modifications

Advanced Cd^II complexes as high efficiency co-sensitizers for enhanced dye-sensitized solar cell performance

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Synthesis and crystal structure of a one-dimensional coordination polymer of nickel(II) with 4′-(imidazol-1-ylmethyl)benzoate anion

Cited by 18 publications

References 13 publications

Supramolecular Coordination Assemblies Constructed From Multifunctional Azole-Containing Carboxylic Acids

Supramolecular Coordination Assemblies Constructed From Multifunctional Azole-Containing Carboxylic Acids

Tailoring the dimensionality of metal complexes via ligand modifications

Advanced CdII complexes as high efficiency co-sensitizers for enhanced dye-sensitized solar cell performance

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Product

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Advanced Cd^II complexes as high efficiency co-sensitizers for enhanced dye-sensitized solar cell performance