Synthesis and crystal structural study of ternary molybdate NaMg3In(MoO4)5

Клевцова, Р. Ф.; Vasiliev, A. D.; Kozhevnikova, N. M.; Glinskaya, L. A.; Kruglik, A. I.; Kotova, I. Yu.

doi:10.1007/bf00753580

Cited by 8 publications

(10 citation statements)

References 2 publications

Supporting

Mentioning

Contrasting

Unclassified

Order By: Relevance

“…NaFe 4 (MoO 4 ) 5 is isotypic to NaMg 3 In(MoO 4 ) 5 (Klevtsova et al, 1993). In the latter compound a random distribution of Mg and In on one site in the ratio 3:1 is reported.…”

Section: Figurementioning

confidence: 86%

Structural investigation of the Na–Fe–Mo–O system

Muessig¹,

Bramnik²,

Ehrenberg³

2003

Acta Crystallogr B Struct Sci

View full text Add to dashboard Cite

Four new crystalline structures within the Na-Fe-Mo-O system are reported: sodium tetrairon pentamolydate (1), NaFe(4)(MoO(4))(5), alpha-sodium diiron trimolybdate (2), alpha-NaFe(2)(MoO(4))(3), beta-sodium diiron trimolybdate (3), beta-NaFe(2)(MoO(4))(3), trisodium diiron trimolybdate (4), Na(3)Fe(2)(MoO(4))(3). All these structures belong to orthomolybdate class of compound and are described as networks of [FeO(6)] octahedra and [MoO(4)] tetrahedra. They are compared with each other and with other related structures.

show abstract

“…NaFe 4 (MoO 4 ) 5 is isotypic to NaMg 3 In(MoO 4 ) 5 (Klevtsova et al, 1993). In the latter compound a random distribution of Mg and In on one site in the ratio 3:1 is reported.…”

Section: Figurementioning

confidence: 86%

Structural investigation of the Na–Fe–Mo–O system

Muessig¹,

Bramnik²,

Ehrenberg³

2003

Acta Crystallogr B Struct Sci

View full text Add to dashboard Cite

show abstract

“…gr. P1, Z = 2) [20]. The diffractograms of the AgA 3 Ga(MoO 4 ) 5 (A = Mn, Co, Zn) were indexed with taking into account our data obtained earlier in the course of single-crystal structure de-termination of AgMg 3 R(MoO 4 ) 5 , R = Fe, Cr [7].…”

Section: Pxrd Characteristicsmentioning

confidence: 99%

Synthesis, crystal structure and electrophysical properties of triple molybdates containing silver, gallium and divalent metals

et al. 2018

Self Cite

View full text Add to dashboard Cite

, crystal structure and electrophysical properties of triple molybdates containing silver, gallium and divalent metals A possibility of the triple molybdates formation with both NASICON-like and NaMg 3 In(MoO 4) 5 structures in the Ag 2 MoO 4-AMoO 4-Ga 2 (MoO 4) 3 (A = Mn, Co, Zn, Ni) systems was studied by powder X-ray diffraction analysis. It was established that NASICON-like phases Ag 1−x A 1−x Ga 1+x (MoO 4) 3 are not formed. The triple molybdates AgA 3 Ga (MoO 4) 5 (A = Mn, Co, Zn) isostructural to triclinic NaMg 3 In(MoO 4) 5 (sp. gr. P1, Z = 2) were synthesized and characterized. The structure of the obtained compounds was refined for AgZn 3 Ga(MoO 4) 5 according to the powder data by the Rietveld method. The structure consists of MoO 4 tetrahedra, couples of edge-shared M(1)O 6 octahedra, and trimers of edge-shared M(2)O 6-, M(3) 6and M(4)O 6 octahedra, which are linked by the common vertices to form a 3D framework. High-temperature conductivity measurements revealed that the conductivity of AgMn 3 Ga(MoO 4) 5 at 500 °С reaches 10-2 S / cm, which is close to one of the known NASICON-type ionic conductors.

show abstract

“…Un examen bibliographie montre que la phase synthé tisé e est isostructurale à celles de formulation NaFe 4 (MoO 4 ) 5 (Muessig et al, 2003), NaMg 3 Al(MoO 4 ) 5 (Hermanowicz et al, 2006) et NaMg 3 In(MoO 4 ) 5 (Klevtsova et al, 1993). La recherche de structures pré sentant des aspects communs avec celle de AgMn II 3 (Mn III 0,26 Al 0,74 )(MoO 4 ) 5 , nous a conduit à la famille des alluaudites et plus pré cisé ment le composé Na 2 FeMn 2 (PO 4 ) 3 (Daidouh et al, 2002) possé dant des dimè res dans les couches.…”

Section: Enquête De Base De Donnéesunclassified

Synthèse et structure cristalline d'un matériau noir AgMn^II₃(Mn^III_0,26Al_0,74)(MoO₄)₅

Bouzidi¹,

Frigui²,

Zid³

2015

Acta Cryst E

View full text Add to dashboard Cite

show abstract

Synthesis and crystal structural study of ternary molybdate NaMg3In(MoO4)5

Cited by 8 publications

References 2 publications

Structural investigation of the Na–Fe–Mo–O system

Structural investigation of the Na–Fe–Mo–O system

Synthesis, crystal structure and electrophysical properties of triple molybdates containing silver, gallium and divalent metals

Synthèse et structure cristalline d'un matériau noir AgMn^II₃(Mn^III_0,26Al_0,74)(MoO₄)₅

Contact Info

Product

Resources

About

Synthesis and crystal structural study of ternary molybdate NaMg3In(MoO4)5

Cited by 8 publications

References 2 publications

Structural investigation of the Na–Fe–Mo–O system

Structural investigation of the Na–Fe–Mo–O system

Synthesis, crystal structure and electrophysical properties of triple molybdates containing silver, gallium and divalent metals

Synthèse et structure cristalline d'un matériau noir AgMnII3(MnIII0,26Al0,74)(MoO4)5

Contact Info

Product

Resources

About

Synthèse et structure cristalline d'un matériau noir AgMn^II₃(Mn^III_0,26Al_0,74)(MoO₄)₅