Synthesis and chemistry of guanidine derivatives

Keywords: Ligand design / N ligands / Tripodal ligands / Coordination chemistry / Manganese / Iron / Zinc / MolybdenumThe synthesis of the novel tripod ligand N[CH 2 CH 2 N= C(NMe 2 ) 2 ] 3 , based on the tris(2-ethylamino)amine (tren) backbone and having a set of three superbasic tetramethylguanidine (TMG) donor atoms instead of the primary amine functionalities, is described. This ligand has been prepared by treating tren with the Vilsmeyer salt [(Me 2 N) 2 CCl]Cl in

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Complexes of Manganese, Iron, Zinc, and Molybdenum with a Superbasic Tris(guanidine) Derivative of Tris(2-ethylamino)amine (Tren) as a Tripod Ligand

Wittmann

Raab

Schorm

et al. 2001

Eur. J. Inorg. Chem.

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Modified Guanidines as Chiral Auxiliaries

Ishikawa

Isobe²

2002

Chem. Eur. J.

214

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1,8-Bis(tetramethylguanidino)naphthalene (TMGN): A New, Superbasic and Kinetically Active “Proton Sponge”

Raab¹,

Kipke²,

Gschwind³

et al. 2002

Chem. Eur. J.

186

168

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Synthesis and chemistry of guanidine derivatives

Cited by 25 publications

References 164 publications

Complexes of Manganese, Iron, Zinc, and Molybdenum with a Superbasic Tris(guanidine) Derivative of Tris(2-ethylamino)amine (Tren) as a Tripod Ligand

Complexes of Manganese, Iron, Zinc, and Molybdenum with a Superbasic Tris(guanidine) Derivative of Tris(2-ethylamino)amine (Tren) as a Tripod Ligand

Modified Guanidines as Chiral Auxiliaries

1,8-Bis(tetramethylguanidino)naphthalene (TMGN): A New, Superbasic and Kinetically Active “Proton Sponge”

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