Synthesis and characterization of η3-allyl palladium(II) complexes with Ph2P(S)CHP(S)Ph2 and OC(CF3)CHCO(C4H3S) co-ligands

Abstract

The new complexes [(g 3

Catechol Oxidase, Phosphatase-Like Activity, DNA/BSA Binding Studies of RuII Complexes of S-Allyldithiocarbazate: Synthesis and Spectral Studies

“…22 Influenced by the above facts, we wish to synthesize S-allyldithiocarbazate, RCH=NNHC(S)SR' and allyl group in the molecular structure of new complexes to bring many interesting chemical behaviors and can be used as a ligand. [23][24][25][26] Ligands exhibit thionethiol tautomer (Scheme 1), N and S donor atoms linked to the metal ion to form six-membered rings. Hopefully, S-allyldithiocarbazate to ruthenium gives better biological performance.…”

Synthesis and Characterization of η3-Allyl Palladium(II) Complexes with Tetraalkyldiphosphine Disulfides, R2P(S)P(S)R2 (R=Me, Et, nPr, nBu, Ph)

“…Halide exchange reactions can also result in the formation of the monomeric ketoamine complexes, [4] amino acid derivatives such as [(η 3 -allyl)Pd(AA)] (AA = glycinato) [5] and bidentate phosphine sulfide complex, [(η 3 -allyl)Pd(Ph 2 P(S)CHP(S)Ph 2 )], have also been reported. [6] Since the preparation of the first tetraalkyldiphosphine disulfide complexes in 1965 such compounds have continued [7][8][9][10][11][12] to attract attention, in part because of the different possible coordination geometries which the ligand may adopt. In the solid state, tetraalkyldiphosphine disulfides have the centrosymmetric trans structure shown in Figure 1.…”