“…The distances of the P-O bond are in the range of 1.508(11)-1.581( 12) Å, and the lengths of W-O vary from 1.715(15) to 2.492(13) Å, which conform to the normal value. 43,44 Different oxidation states of the W ions and Cu ions were further confirmed by XPS measurement (Fig. 2).…”
A novel type of polyoxometalate-based metal–organic complex was successfully synthesized, which showed good catalytic activity for the oxidation of alkylbenzenes with high conversion, excellent selectivity, and rapid reaction time.
“…The distances of the P-O bond are in the range of 1.508(11)-1.581( 12) Å, and the lengths of W-O vary from 1.715(15) to 2.492(13) Å, which conform to the normal value. 43,44 Different oxidation states of the W ions and Cu ions were further confirmed by XPS measurement (Fig. 2).…”
A novel type of polyoxometalate-based metal–organic complex was successfully synthesized, which showed good catalytic activity for the oxidation of alkylbenzenes with high conversion, excellent selectivity, and rapid reaction time.
Silver‐Tungsten‐Oxide Frameworks: Isomerically pure forms of the unique isopolyoxotungstate system are incorporated into highly connected framework materials using Ag(I) as a linking unit. Thermal treatment of the materials leads to the formation of silver microparticles embedded in a tungsten oxide matrix. This novel synthetic approach promises to create a new class of nanostructured tungsten‐silver‐oxides with exciting physical properties, as well as exemplifies the potential for new frameworks based upon solution processable POM clusters.
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