Synthesis and characterization of silver(I) complexes with <i>N</i>‐thiophosphorylated thiobenzamide or thiourea and phosphines

Babashkina, Maria G.; Safin, Damir A.; Klein, Axel

doi:10.1002/hc.20627

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Phosphine Chalcogen and Related Ligands1

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Cited by 7 publications

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References 19 publications

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“…184 Cycloaurated phosphine chalcogenates with sulfur and selenium can by generated from mercury precursors. 185 Several dinuclear silver(I) complexes with pyridinethiolates or -selenolates 186 as well as N-thiophosphorylated thiobenzamide or thiourea 187 and bis(phosphines) were reported.…”

Section: Phosphine Chalcogen and Related Ligandsmentioning

confidence: 99%

Silver and gold

Meyer

Schuh

Mohr

2011

Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem.

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Section: Phosphine Chalcogen and Related Ligandsmentioning

confidence: 99%

Silver and gold

Meyer

Schuh

Mohr

2011

Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem.

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Supramolecular Coordination Complexes of theN‐Thiophosphorylated 2,5‐Dithiobiurea [NHC(S)NHP(S)(OiPr)₂]₂with Zn^IIand Cd^IIIons – Cation‐Induced Dinuclear Mesocate Structure versus Tetranuclear Nanoscaled Aggregate

et al. 2014

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The reaction of the deprotonated N‐thiophosphorylated bisthiourea N,N′‐bis(diisopropoxythiophosphorylamidothiocarbonyl)hydrazine {[NHC(S)NHP(S)(OiPr)2]2, H2L} with ZnCl2 leads to the complex [Zn2{[NHC(S)NP(S)(OiPr)2]2}2] ([Zn2L2]), in which two metal cations are each 1,5‐S,S′‐coordinated through the sulfur atoms of the thiocarbonyl and thiophosphoryl groups of the pendant deprotonated thioacylamidothiophosphate functions. The same reaction with CdCl2 leads to the tetranuclear nanoscaled aggregate [(Cd2{[NC(S)NHP(S)(OiPr)2]2}2)2] ([(Cd2L2)2]). This complex contains ligands that are doubly deprotonated through their hydrazine NH groups and exhibit unprecedented μ4 and μ5 coordination modes. DFT calculations have shown that both complexes are stabilized not only by typical coordination bonds (Zn–S, Cd–S) but also by numerous intramolecular “noncovalent” interactions: polar C–H···S and N–H···S, nonpolar C–H···H–C, and σ‐hole bonding (S···S).

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Decomposition of the mixed-ligand silver(I) complex [Ag(PPh3)2{Et2NC(S)NP(S)(OiPr)2}] with the formation of [Ag(PPh3){Et2NC(S)NP(S)(OiPr)2}], [Ag(PPh3)3NCS]∙(CH3)2 C=O and Et2NP(S)(OiPr)2

Babashkina

Safin

Bolte

et al. 2012

Inorganic Chemistry Communications

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Synthesis and characterization of silver(I) complexes with N‐thiophosphorylated thiobenzamide or thiourea and phosphines

Abstract: A reaction of the potassium salts of RC(S)NHP(S)(OiPr) 2 (R =PhNH

Cited by 7 publications

References 19 publications

Silver and gold

Silver and gold

Supramolecular Coordination Complexes of theN‐Thiophosphorylated 2,5‐Dithiobiurea [NHC(S)NHP(S)(OiPr)₂]₂with Zn^IIand Cd^IIIons – Cation‐Induced Dinuclear Mesocate Structure versus Tetranuclear Nanoscaled Aggregate

Decomposition of the mixed-ligand silver(I) complex [Ag(PPh3)2{Et2NC(S)NP(S)(OiPr)2}] with the formation of [Ag(PPh3){Et2NC(S)NP(S)(OiPr)2}], [Ag(PPh3)3NCS]∙(CH3)2 C=O and Et2NP(S)(OiPr)2

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Synthesis and characterization of silver(I) complexes with N‐thiophosphorylated thiobenzamide or thiourea and phosphines

Abstract: A reaction of the potassium salts of RC(S)NHP(S)(OiPr) 2 (R =PhNH

Cited by 7 publications

References 19 publications

Silver and gold

Silver and gold

Supramolecular Coordination Complexes of theN‐Thiophosphorylated 2,5‐Dithiobiurea [NHC(S)NHP(S)(OiPr)2]2with ZnIIand CdIIIons – Cation‐Induced Dinuclear Mesocate Structure versus Tetranuclear Nanoscaled Aggregate

Decomposition of the mixed-ligand silver(I) complex [Ag(PPh3)2{Et2NC(S)NP(S)(OiPr)2}] with the formation of [Ag(PPh3){Et2NC(S)NP(S)(OiPr)2}], [Ag(PPh3)3NCS]∙(CH3)2 C=O and Et2NP(S)(OiPr)2

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Supramolecular Coordination Complexes of theN‐Thiophosphorylated 2,5‐Dithiobiurea [NHC(S)NHP(S)(OiPr)₂]₂with Zn^IIand Cd^IIIons – Cation‐Induced Dinuclear Mesocate Structure versus Tetranuclear Nanoscaled Aggregate