Synthesis and Characterization of Ruthenium and Iron−Ruthenium Prussian Blue Analogues

Behera, J. N.; D’Alessandro, Deanna M.; Soheilnia, Navid; Long, Jeffrey R.

doi:10.1021/cm900230p

Cited by 74 publications

(58 citation statements)

References 50 publications

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“…Prussian Blue analogs have been intensively investigated as Li + conductors for potential applications in Li ion batteries. 59 Long et al recently reported a Li + conductive MOF via addition of lithium isopropoxide to a MOF with open metal sites. 60 Proton conductivities of inorganic or organic compounds, such as zirconium phosphate, metal oxides, and Nafion, have been studied for applications in fuel cells and sensors.…”

Section: Electro- and Photo-active Mofs For Energy Conversion And Stomentioning

confidence: 99%

Metal–Organic Frameworks as A Tunable Platform for Designing Functional Molecular Materials

2013

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Metal-organic frameworks (MOFs), also known as coordination polymers, represent an interesting class of crystalline molecular materials that are synthesized by combining metal-connecting points and bridging ligands. The modular nature of and mild conditions for MOF synthesis have permitted the rational structural design of numerous MOFs and the incorporation of various functionalities via constituent building blocks. The resulting designer MOFs have shown promise for applications in a number of areas, including gas storage/separation, nonlinear optics/ferroelectricity, catalysis, energy conversion/storage, chemical sensing, biomedical imaging, and drug delivery. The structure-property relationships of MOFs can also be readily established by taking advantage of the knowledge of their detailed atomic structures, which enables fine-tuning of their functionalities for desired applications. Through the combination of molecular synthesis and crystal engineering MOFs thus present an unprecedented opportunity for the rational and precise design of functional materials.

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Section: Electro- and Photo-active Mofs For Energy Conversion And Stomentioning

confidence: 99%

Metal–Organic Frameworks as A Tunable Platform for Designing Functional Molecular Materials

2013

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“…Nevertheless, MOFs have been successfully used as electrode materials for rechargeable batteries 30,31 and strategies have been envisaged to overcome their insulating character. [32][33][34][35] The redox behaviour of metal cations inside MOFs could provide a pathway for electrons. 33 Alternatively, the tuning of the linker structure may lead to better charge transfer inside the framework.…”

Section: Broader Contextmentioning

confidence: 99%

“…33 Alternatively, the tuning of the linker structure may lead to better charge transfer inside the framework. 34 A bolder but efficient strategy is to mix MOFs with conductive phases (metal nanocrystals, carbon nanostructures, conductive polymers, etc.). 32,35,36 This will however provide electron conduction at a macroscopic level, but not necessarily locally inside the MOF particles due to size-exclusion effects defined by the pore apertures.…”

Section: Broader Contextmentioning

confidence: 99%

Metal organic frameworks for electrochemical applications

Morozan

Jaouen

2012

Energy Environ. Sci.

779

456

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Metal-organic frameworks (MOFs) have received huge attention in the last years as promising porous materials with unrivalled degree of tunability for a wide range of applications including gas storage or separation, catalysis, drug delivery and imaging. The present review appraises the application of MOFs in the field of electrochemistry. From materials for rechargeable batteries, supercapacitors and fuel cells to electrocatalysis or corrosion inhibition, MOFs or MOF-derived materials are gaining momentum in this field. For real breakthroughs, combining their electrochemical properties with appropriate electronic and ionic conductivity will be required.

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“…Por ejemplo, observamos como el solo hecho de sustituir un metal por otro, en un compuesto, hace que surjan nuevas propiedades magnéticas (Coronado y Gatteshi, 2006). Los modelos de Ising mixtos juegan un papel importante en la simulación de dichas propiedades (Keskin y Polat, 2009;Behera et al, 2009). Se han realizado, por diversos métodos, diferentes estudios sobre estos modelos compuestos por dos o más subredes de espines mixtos (De La Espriella y Buendía, 2011;De La Espriella y Buendía, 2010;Deviren y Keskin, 2010;Yessoufou et al, 2009;Albayrak e Yigit, 2007;Buendía y Villarroel, 2007;Zhang et al, 2005;Htoutou et al, 2004;Zaim et al, 2009;Ekiz, 2008;Ekiz, 2005;Albayrak e Yigit, 2006).…”

Section: Introductionunclassified

Estudio Monte Carlo de un Ferrimagneto de Ising Mixto con Diferentes Anisotropías

2012

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ResumenMediante simulaciones de Monte Carlo, se analizan las propiedades magnéticas de un modelo ferrimagnético de Ising mixto, con espines S = ±3/2, ±1/2 y σ = ±5/2, ±3/2, ±1/2 distribuidos sobre una red cuadrada, con diferentes anisotropías. Se supuso que la interacción de intercambio a primeros vecinos, J 1 , entre espines S y σ es antiferromagnética (J 1 < 0). También, se consideró el efecto de las intensidades de las anisotropías de ión simple, debidas a los campos cristalinos de las subredes S y σ, D S y D σ , respectivamente. Se investigó la existencia y dependencia de las temperaturas de compensación del modelo con respecto a las anisotropías de ión simple. Fijando el parámetro D S y variando la intensidad de D σ , aparecen posibles transiciones de fase de primer orden. El análisis de las temperaturas críticas se obtiene a través de los máximos del calor específico del sistema. Los diagramas de fase a temperaturas finitas se obtienen en el plano temperatura-anisotropía. Abstract Using MonteCarlo simulations, the magnetic properties of a mixed Ising ferrimagnetic model with spins S = ±3/2, ±1/2 y σ = ±5/2, ±3/2, ±1/2 distributed on a square lattice with different anisotropies was analyzed. It was assumed that the exchange interaction to nearest neighbors, J 1 , between spins S and σ, is antiferromagnetic (J 1 < 0). Also, it was considered that the effect of the intensities of the single-ion anisotropies, due to the crystalline fields of the sublattices S and σ, D S and D σ respectively. The existence and dependence of the compensation temperature in the model with respect to the single-ion anisotropies was also studied. By fixing the parameter D S and varying the intensity of D σ it probable phase transitions of first order appear. The analysis of the critical temperatures is obtained through the maximum of the specific heat of the system. Phase diagrams at finite temperatures are obtained in the temperature-anisotropy plane.

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Synthesis and Characterization of Ruthenium and Iron−Ruthenium Prussian Blue Analogues

Cited by 74 publications

References 50 publications

Metal–Organic Frameworks as A Tunable Platform for Designing Functional Molecular Materials

Metal–Organic Frameworks as A Tunable Platform for Designing Functional Molecular Materials

Metal organic frameworks for electrochemical applications

Estudio Monte Carlo de un Ferrimagneto de Ising Mixto con Diferentes Anisotropías

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