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Cited by 3 publications
(2 citation statements)
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References 24 publications
(35 reference statements)
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“…The doubly deprotonated form, L 2− , is an effective dinucleating ligand that readily forms bioctahedral complexes of the type [M 2 L( μ ‐L′)] + with various first‐row transition metal ions (M=Mn 2+ , Fe 2+ , Co 2+ , Co 3+ , Ni 2+ , Figure 1 ). [38] Several co‐ligands such as L′=Cl − , OH − , [39] HS − , [40] and RCO 2 − ,[ 41 , 42 , 43 , 44 , 45 , 46 ] to name just a few, can be accommodated between the divalent metal ions. Complexes of this kind offer the opportunity to investigate intramolecular magnetic super‐exchange interaction as a function of the electronic configuration of the metal ions and the type of the coligand.…”
Section: Introductionmentioning
confidence: 99%
“…The doubly deprotonated form, L 2− , is an effective dinucleating ligand that readily forms bioctahedral complexes of the type [M 2 L( μ ‐L′)] + with various first‐row transition metal ions (M=Mn 2+ , Fe 2+ , Co 2+ , Co 3+ , Ni 2+ , Figure 1 ). [38] Several co‐ligands such as L′=Cl − , OH − , [39] HS − , [40] and RCO 2 − ,[ 41 , 42 , 43 , 44 , 45 , 46 ] to name just a few, can be accommodated between the divalent metal ions. Complexes of this kind offer the opportunity to investigate intramolecular magnetic super‐exchange interaction as a function of the electronic configuration of the metal ions and the type of the coligand.…”
Section: Introductionmentioning
confidence: 99%
“…We have also described related [{Ni 2 L} 2 (μ‐dppba) 2 M L′ 2 ] 2+ complexes, where a metallodicarboxylato ligand, namely [ M L′ 2 (dppba) 2 ] 2– [dppba = 4‐(diphenylphosphanyl)benzoate; M = Pd II , Rh I , Pt II ; L′ = Cl – , Br – , I – ], is encapsulated by the two {Ni 2 L} hemispheres 5. These compounds could be prepared in much the same way as those bearing the purely organic dicarboxylato ligands, i.e.…”
Section: Introductionmentioning
confidence: 99%