Abstract:The strategy of modifying phosphane ligands through substituent variation has been widely applied in coordination chemistry and catalysis. This contribution focuses on unsymmetric ferrocene diphosphanes with electronically distinct phosphane moieties, Ph 2 PfcCH 2 PAr 2 (Ar=Ph, 1; 3,5-C 6 H 3 Me 2 , 2; and 3,5-C 6 H 3 (CF 3 ) 2 , 3; fc = ferrocene-1,1'-diyl), which were synthesized and converted to the corresponding selenides (1Se-3Se) and Pd(0) complexes [Pd(L-k 2 P,P')(η 2 -ma)] (5-8 for L = 1-3 and dppf, ma… Show more
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