“…In the spectrum of P-PVA, the characteristic bands of the O-H stretching around 3250 cm -1 , the -CH 2 stretching (symmetric and asymmetric) at 2903 and 2810 cm -1 , the C-H bending at 1407 cm -1 are observed, and the absorbance peak at 1026 cm -1 is attributed to the stretching frequency of the -P-O-C-groups, and the strong absorbance peak at 1690 cm -1 is assigned to the stretching vibration of the -P=O-groups. 35 In the spectrum of the PAn ES, the characteristic peaks at 1502 and 1630 cm -1 are assigned to the non-symmetric benzene ring stretching vibration, the bonds around 1280 cm -1 are attributed to the stretching vibration of the C-N (mode of -N-benzenoid-N-), 36 the peak at 1130 cm -1 is assigned to the in-plane-bending vibration of the C-H (mode of -N= quinoid=N-and quinoid=N + H-benzenoid), 37 and the peak at 3525 cm -1 is assigned to the N-H stretching, respectively. In the spectrum of the PAn/P-PVA nanoparticles, the strong absorbance peak at 1060 cm -1 is assigned to the overlap of the absorbance frequency of the -P-O-C-groups of P-PVA and the in-plane-bending vibration of the C-H of PAn.…”