Synthesis and characterization of novel organogallium-phosphorus compounds: x-ray crystal structures of [cyclic] Ph2GaP(SiMe3)2Ga(Ph)2Cl, Ph2(Cl)Ga.cntdot.P(SiMe3)3, and Ph3Ga.cntdot.P(SiMe3)3

Coordination chemistry of the main group elements with phosphine, arsine and stibine ligands

“…The syntheses are straightforward involving combining the GaR 3 with ER 3 either in a hydrocarbon or without a solvent [141,194,196,198,199,201]. Triarylgallium examples are fewer but generally similar [198,203].…”

“…The syntheses are straightforward involving combining the GaR 3 with ER 3 either in a hydrocarbon or without a solvent [141,194,196,198,199,201]. Triarylgallium examples are fewer but generally similar [198,203]. Di-and poly-phosphine adducts are also known [141,146,202] and all contain only a single phosphorus donor bonded to each gallium centre.…”

“…32), although these are particularly sensitive compounds, and contain much weaker Ga-E bonds than the lighter Group 15 analogues [149,154,[192][193][194][195]200]. Phosphine and arsine adducts of R 2 GaCl (R = Me, Me 3 CCH 2 , Ph) have been prepared [197,198,202]. There are also examples of (Fig.…”

Synthesis and molecular structures of R(Me3CCH2)2In · E(SiMe3)3 (R=Me3CCH2, E = P or As; R = Me, E = P).

“…(MGa, E = As 2 , 4 , 5 or p; 8 M = In, E = P 6 or As 7 ) core. Additionally, adducts of the type R 3 M'E(SiMe 3 ) 3 (R = Me3SiCH 2 , M = In, E = As; 9 R = Ph 9 or C 6 Fs,'° M = Ga, E = As) and R 2 (CI)M'E(SiMe 3 ) 3 (R = Me 3 CCH 2 , M = Ga, E = As; 5 R = Ph, M = Ga, E = P; 8 …”

Synthesis and characterization of [(Me3SiCH2)2GaP(SiMe3)2]2, an example of a gallium-phosphorus dimer obtainable only through an indirect reaction pathway

“…These include compounds containing a four-membered ring core of the form Ga-P-Ga-P [1,2], as well as the mixed-bridge type core Ga-P-Ga-Cl [3]. When the bulky (trimethylsilyl)methyl-and neopentyl-groups were attached to the gallium atom in an effort to influence the oligomerization of the final products, several interesting rearrangements occurred [4].…”