Synthesis and characterization of new Mg–O–F system and its application as catalytic support

Hydrodechlorination of Tetrachloromethane over Palladium Catalysts Supported on Mixed MgF2-MgO Carriers

“…By increasing the fluorine content of the magnesium oxide fluoride, the Lewis acidity increases whereas the basicity decreases [30]. This correlation is also compatible with recent results on toluene hydrogenation over Ir/MgO-MgF 2 catalysts [53], where the best iridium catalysts were supported on MgF 2 -rich carriers characterized by a relatively low surface basicity.…”

Upgrading of furfural to biofuel precursors via aldol condensation with acetone over magnesium hydroxide fluorides MgF2−x(OH)x

“…Such solids were successfully used as either basic catalysts for the Michael addition of 2-methylcyclohexane-1,3-dione to methyl vinyl ketone (25 °C, atmospheric pressure) 35 or catalytic support. [36][37][38][39][40] Moreover, the use of solid basic catalysts involves generally an activation step at high temperature to active basic sites by removal of carbonate species.…”

Synthesis and characterization of MgF2–CoF2 binary fluorides. Influence of the treatment atmosphere and temperature on the structure and surface properties

“…The commercial importance of inorganic uorides is mainly a result of their application in metallurgy (rare-earth metals, aluminum, hafnium, zirconium), isotope separation and the manufacture of optical materials such as antireective coatings. However, recently an increase has been observed in the interest in the application of inorganic uorides in such areas as catalysis, [1][2][3][4][5][6][7] photonics, [8][9][10] biosensing, 11 reversible positive electrodes for rechargeable lithium batteries, [12][13][14][15][16][17][18] high-temperature superconductor devices 8 and supercapacitors. 19 To tailor the properties of inorganic uorides to the above applications, it is necessary to either use new ways of preparation 15,16,[20][21][22][23][24][25][26][27] or to modify already known materials, among other things by isomorphic substitution of cations in the structure of a host with cations of a guest.…”