Synthesis and Characterization of New N‐Heterocyclic Silylazides

Abstract

Three novel pyridine functionalized N-heterocyclic silanes, bearing chloride and azide moieties, were synthesized and characterized by NMR spectroscopy ( 1 H, 13 C, 29 Si), mass spectrometry, elemental analysis, and single-crystal XRD. The molecular structures show a comparably strong dative interaction of the pyridine-N with the Si center, formally inducing a penta-coordination arrangement at