Synthesis and characterization of naphthalimide-functionalized polynorbornenes

Hollauf, Manuel; Čajlaković, Merima; Tscherner, Martin; Köstler, Stefan; Knall, Astrid‐Caroline; Trimmel, Gregor

doi:10.1007/s00706-016-1887-3

Cited by 9 publications

(5 citation statements)

References 35 publications

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“…It has been reported that PNB obtained by nickel catalysts could be dissolved in chlorobenzene at room temperature in the 2000s, and the solubility and processability of PNB have been improved. 5,7 Introducing polar groups [8][9][10][11] or exible chains 12,13 into the PNB backbone has become an effective means of solving the problem. The design and synthesis of particularly efficient and stable catalysts is very important for the polymerization.…”

Section: Introductionmentioning

confidence: 99%

Synthesis of bis-(benzocyclohexan-ketoimino) Ni(ii) with different electron groups and their catalytic copolymerization of norbornene and polar norbornene

Yang

Wang

et al. 2017

RSC Adv.

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Section: Introductionmentioning

confidence: 99%

Synthesis of bis-(benzocyclohexan-ketoimino) Ni(ii) with different electron groups and their catalytic copolymerization of norbornene and polar norbornene

Yang

Wang

et al. 2017

RSC Adv.

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“…A noticeable advantage of the optical platform of 1,8-naphthalimide is the possibility of adjusting the optical properties by varying substituents in the 4th position of the naphthalimide nucleus. For example, a replacement of nitrogen atom by an oxygen allows to shift the fluorescence maximum to the blue range of spectrum [64].…”

Section: Methodsmentioning

confidence: 99%

Synthesis and applications of fluorescent-tagged scale inhibitors in water treatment. A review

Oshchepkov¹,

Tkachenko²,

Popov³

2019

Int. J. Corros. Scale Inhib.

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Fluorescent-tagged scale inhibitor application is a new trend in water treatment. An increasing interest to the fluorescent antiscalants is associated with a need of a better scale inhibitor concentration control in industrial applications: the concentration of antiscalants in the circulating system is usually changed by evaporation of water, reagent sorption on the pipe surfaces and on scale particles, as well as by a periodical discharge of the circulating water with some deposit. This paper considers synthesis, properties and industrial applications of antiscalants bearing a fluorescent fragment. A special focus is done on the covalent implementation of the fluorescent fragment into the polymer matrix, performed in two different ways: (a) the first one includes attachment along with the polymer formation process; (b) the second one is based on the fluorophore binding to the ready-made polymer matrix. An attachment of a fluorescent fragment to the bisphosphonate is also described. Besides the issues of antiscalant concentration monitoring in industrial facilities, the unique opportunity of the scale inhibition theory development via the direct visualization of fluorescent-tagged scale inhibitors in various scale formation processes is demonstrated. A recent progress in scale inhibition mechanism understanding due to an antiscalant visualization in situ is highlighted.

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“…Functional polymers that are able to detect pH attract considerable attention because of their potential application in biology. A series of sensing polymers were prepared, in which naphthalimide derivatives were copolymerized with different monomers such as methyl methacrylate, styrene, 2‐hydroxyethyl methacrylate, [ 56 ] dimethylbicyclo[2.2.1] hept‐5‐ene‐2,3‐dicarboxylate [ 57 ] and acrylamide. Alkylpiperazine derivative of naphthalimides belong to the most popular structures, since they show best sensitivity, even in the complex media.…”

Section: Sensors For Cationsmentioning

confidence: 99%

Naphthalimide‐Based Fluorescent Polymers for Molecular Detection

Oshchepkov

Oshchepkova

et al. 2021

Advanced Optical Materials

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The beginning of the 21st century was marked by the intensive development of fiber‐optic sensors. New functional materials with excellent sensory properties are required to design such sensors. Fluorescent probes for neutral and charged molecules are constantly developing. However, only a small part of the reported probes was successfully converted into functional sensing polymers and found real‐world applications. A great challenge is to retain the sensing properties of a probe in a polymer matrix. The purpose of this review is to understand how properties of a probe are changed upon incorporation into a polymer and to reveal successful approaches. The review focuses on the use of the naphthalimide‐based probes in the construction of sensing polymers. The literature overview is presented according to the nature of the guest molecules targeted for the quantitative detection: cations, anions, and small organic molecules.

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Synthesis and characterization of naphthalimide-functionalized polynorbornenes

Cited by 9 publications

References 35 publications

Synthesis of bis-(benzocyclohexan-ketoimino) Ni(ii) with different electron groups and their catalytic copolymerization of norbornene and polar norbornene

Synthesis of bis-(benzocyclohexan-ketoimino) Ni(ii) with different electron groups and their catalytic copolymerization of norbornene and polar norbornene

Synthesis and applications of fluorescent-tagged scale inhibitors in water treatment. A review

Naphthalimide‐Based Fluorescent Polymers for Molecular Detection

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