Synthesis and characterization of nano-scale Terbium (III)-trimesic acid (TMA)-1,10-phenanthroline(phen) luminescent complex

Chun, Zheng; Ren, Huijuan; Cui, Zhenfeng; Chen, Fenghua; Hong, Guangyan

doi:10.1016/j.jallcom.2008.09.201

Cited by 33 publications

(9 citation statements)

References 16 publications

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“…However, search for facile and easy synthetic route for safe conversion of 1,3-diketonate lanthanide complexes into nanoparticulate form is still challenging task. The nanoprecipitation route is widely applied for transformation of different lanthanide complexes into nanoparticles [ 95 , 96 ]. This method can be based on generation of the nano-aggregates from water soluble molecules and ions as it is shown in Figure 10 [ 97 ].…”

Section: Nanoparticulate Forms Of Cyclophanic 13-diketonate Complmentioning

confidence: 99%

1,3-Diketone Calix[4]arene Derivatives—A New Type of Versatile Ligands for Metal Complexes and Nanoparticles

2021

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The present review is aimed at highlighting outlooks for cyclophanic 1,3-diketones as a new type of versatile ligands and building blocks of the nanomaterial for sensing and bioimaging. Thus, the main synthetic routes for achieving the structural diversity of cyclophanic 1,3-diketones are discussed. The structural diversity is demonstrated by variation of both cyclophanic backbones (calix[4]arene, calix[4]resorcinarene and thiacalix[4]arene) and embedding of different substituents onto lower or upper macrocyclic rims. The structural features of the cyclophanic 1,3-diketones are correlated with their ability to form lanthanide complexes exhibiting both lanthanide-centered luminescence and magnetic relaxivity parameters convenient for contrast effect in magnetic resonance imaging (MRI). The revealed structure–property relationships and the applicability of facile one-pot transformation of the complexes to hydrophilic nanoparticles demonstrates the advantages of 1,3-diketone calix[4]arene ligands and their complexes in developing of nanomaterials for sensing and bioimaging.

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Section: Nanoparticulate Forms Of Cyclophanic 13-diketonate Complmentioning

confidence: 99%

1,3-Diketone Calix[4]arene Derivatives—A New Type of Versatile Ligands for Metal Complexes and Nanoparticles

2021

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“…For instance, Zheng et al prepared a terbium complex containing trimesic acid with an optimal excitation wavelength at 255 nm. 18 Nasso et al reported a terbium complex of 6-methyl-2-(3-ethoxycarbonylpyrazol-1-yl)pyridine with the an optimal excitation wavelength at 301 nm. 19 Guo and co-workers prepared a terbium complex containing benzoic acid with an excitation band between 250-360 nm.…”

Section: Introductionmentioning

confidence: 99%

Tunable white light emission of Eu,Tb,Zn-containing copolymers by RAFT polymerization

Zhang

Sun

et al. 2015

J. Mater. Chem. C

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In this work, a novel copolymer PS-Eu-Tb-Zn, which can match 365 nm UV chip, was synthesized by RAFT polymerization of Tb(p-BBA) 3 UA, Eu(TTA) 2 (Phen)MAA, Zn(BTZ)UA and styrene. TG-DTG and PL analyses indicate that copolymer PS-Eu-Tb-Zn displays favorable thermal stability and luminescent properties. Excited at 365 nm, the copolymer exhibits emission peaks at 421 nm (blue emission), 488, 543 nm (green emission), 589 and 615 nm (red emission). The white light of the copolymer can be obtained by tuning the ratios of three complexes and excitation wavelengths. The CIE coordinates (0.352, 0.330) of the copolymer is optimal upon excitation at 365 nm. For the fabricated white LED using 365 nm UV chip with the copolymer, the CCT is 5684 K, and the CRI is 83.1. All the results indicate that the copolymer can be applied as a phosphor for fabrication of NUV-based white LED.performance. Moreover, the optical properties of the fabricated WLED also show that the CCT is 5684 K, the CRI (R a ) is 83.1. In comparison with the WLED based on blue InGaN chip and YAG:Ce 3+ phosphor (R a =75, CCT=7756 K), 62,63 the WLED in this study shows higher R a value and lower CCT value, indicating copolymer 5 can be a promising candidate for application in NUV-based white LED.

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“…Due to the attractive photophysical properties of lanthanide ions, it is a popular strategy to utilize lanthanide ions to form a highly luminescent material [3][4][5][6][7][8][9][10][11][12]. Meanwhile metal-organic frameworks (MOFs) have rapidly gained growing attention due to the characteristics such as structure diversity, predictability and high porosity [13,14].…”

Section: Introductionmentioning

confidence: 99%

A metal–organic framework for selectively sensing of PO43− anion in aqueous solution

Xiao

Rao

et al. 2011

Journal of Alloys and Compounds

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Synthesis and characterization of nano-scale Terbium (III)-trimesic acid (TMA)-1,10-phenanthroline(phen) luminescent complex

Cited by 33 publications

References 16 publications

1,3-Diketone Calix[4]arene Derivatives—A New Type of Versatile Ligands for Metal Complexes and Nanoparticles

1,3-Diketone Calix[4]arene Derivatives—A New Type of Versatile Ligands for Metal Complexes and Nanoparticles

Tunable white light emission of Eu,Tb,Zn-containing copolymers by RAFT polymerization

A metal–organic framework for selectively sensing of PO43− anion in aqueous solution

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