Synthesis and characterization of mononuclear copper(II) and cadmium(II) complexes with di-(2-picolyl)sulfur

Choi, Ki‐Young; Shin, Han-Back; Kim, Moon-Jip

doi:10.1007/s11224-006-9142-x

Cited by 3 publications

(2 citation statements)

References 24 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Compared with CVs of the complex, the ligand exhibits an analog broad current respond around 0.7-1.2 V. Therefore, we propose that the response at the range of 0.2-0.9 V is due to the electrochemical reaction of the ligand on the electrode. According to the above analysis, it can be concluded that the oxidation peak (Ep = -0.7 V) is probably assigned to the oxidation peak of Cd ?2 /Cd 0 , and because of the absence of the corresponding reduction peak, the oxidation of the complex can be considered as an irreversible process, similar with the reported [45,46].…”

Section: Electrochemical Properties Of the Complex [Cd(pmp) 2 ] Nsupporting

confidence: 79%

Synthesis, crystal structure, and properties of a three-dimensional coordination polymer [Cd(PMP)2] n

Shuan

et al. 2010

Struct Chem

View full text Add to dashboard Cite

A new Cd(II) coordination polymer, [Cd(PMP) 2 ] n (1) [PMP = 1-phenyl-3-methyl-5-pyrazolone], has been synthesized by the reaction of Cd(CH 3 COO) 2 Á2H 2 O with PMP and characterized by elemental analysis, IR spectrum, fluorescence spectrum, UV-vis spectrum, TG-DTA, and electrochemical analysis. Single crystal X-ray diffraction reveals that the complex has a three-dimensional network. Each PMP acts as bidentate bridging ligand and each Cd(II) center is surrounded by two O atoms and two N atoms from four different PMP ligands to form distorted tetrahedral coordination geometry. The photoluminescence study shows the complex exhibited strong solid state blue fluorescent emission at room temperature, and the TG-DTA analysis demonstrated that it has highly thermal stability. Furthermore, the electrochemical property of the complex has been investigated for the first time in DMF by cyclic voltammetry, and the results showed that it has an irreversible process.

show abstract

Section: Electrochemical Properties Of the Complex [Cd(pmp) 2 ] Nsupporting

confidence: 79%

Synthesis, crystal structure, and properties of a three-dimensional coordination polymer [Cd(PMP)2] n

Shuan

et al. 2010

Struct Chem

View full text Add to dashboard Cite

show abstract

“…Next, mononuclear Cu(II) and Cd(II) complexes with di-(2-picolyl)sulfide were synthesized and characterized by Choi et al [137]. The divalent and trivalent transition metal complexes with NNS and NNN donor ligands have been of great interest because of their importance as an analytical chelate reagent, for biological and bacteriostatic activity [138][139][140][141][142][143].…”

Section: Issuementioning

confidence: 99%

Interplay of thermochemistry and Structural Chemistry, the journal (volume 18, 2007) and the discipline

Ponikvar

Liebman

2008

Struct Chem

View full text Add to dashboard Cite

In this study, we relate the contents of the journal Structural Chemistry for the calendar year 2007 and thermochemistry. The year's articles were briefly summarized and a thermochemical comment written to supplement them. Frequently questions were asked and future research was suggested.Keywords Structural Chemistry Á Thermochemistry Á Thermodynamics Á Enthalpy of formation Á Enthalpy of phase change Á Enthalpy of reaction As practiced disciplines, structural chemistry and thermochemistry are very often unrelated. In this study, these disciplines are linked as relations are explicitly made using the contents of the journal Structural Chemistry (Vol. 18) for the calendar year 2007 as a scaffold for our analysis, for our selected articles in the discipline of structural chemistry. These studies have been reviewed by us, where we give them a thermochemical flavor. While this commentary is most generally written in terms of brief summaries of literature papers involving enthalpies of formation and/or reaction, not uncommonly we raise questions and even suggest possible future research. We are not, however, going to give a thermochemical slant on book reviews, honorary dedications, and obituaries although these works will be cited in our text.As such, this article is a sequel to our earlier related reviews of Structural Chemistry for the calendar years 2000 through 2004 [1-5]. Reviews for 2005 and 2006 are currently being prepared. Issue 1In the first article in the first issue of Structural Chemistry for 2007, Hargittai [6] asserted that while research is currently usually carried out in big groups, the most important ideas, observations and discoveries still belong to individuals who have to bring down dogmas or open entirely new areas in science. This may bring solace to the thermochemical community in which research groups are generally small, and the number of new practitioners sadly few.In the past decade, the crystal engineering of multidimensional arrays and networks containing metal ions has achieved considerable progress because of the increased interest in the potential utility of these compounds as zeolite-like materials [7-11], catalysts [12], or magnetic materials [13][14][15]. The thermochemistry of these species is complicated by their inherent complexity: however, estimation approaches of their key thermochemical quantities are increasingly reliable [16]. In the second article of this issue, by Wang et al. [17], the versatility of malonate dianion as a ligand for the construction of extended networks with different topologies dependent on the coordination geometry of the metal ion was discussed. The synthesis and structure of a novel malonate-bridged copper(II) compound in which copper(II) ions have two different coordination environments in a novel three-dimensional (3D) network was described. Metal malonates have been studied from a

show abstract

Syntheses, crystal structures and properties of six coordination compounds with flexible dps ligand

Sun¹,

Xu²,

Ge³

et al. 2011

Polyhedron

View full text Add to dashboard Cite

Synthesis and characterization of mononuclear copper(II) and cadmium(II) complexes with di-(2-picolyl)sulfur

Cited by 3 publications

References 24 publications

Synthesis, crystal structure, and properties of a three-dimensional coordination polymer [Cd(PMP)2] n

Synthesis, crystal structure, and properties of a three-dimensional coordination polymer [Cd(PMP)2] n

Interplay of thermochemistry and Structural Chemistry, the journal (volume 18, 2007) and the discipline

Syntheses, crystal structures and properties of six coordination compounds with flexible dps ligand

Contact Info

Product

Resources

About