ABSTRACT:The ring-opening polymerization of ɛ-caprolactone and morpholine mixture was carried out at 160°C for 24 h under nitrogen atmosphere at two different experimental conditions, mercaptoaceticacid (MAA) and Ag-MAA initiator variation. The resultants were characterized by Fourier transform infrared spectroscopy, differential scanning calorimetry, thermogravimetric analysis, gel permeation chromatography, and high-resolution transmission electron microscopy techniques. The tensile strength of the copolymer nanocomposites was tested. The catalytic reduction behavior (reduction of nitrophenol into amino phenol), splinting activity, and drug delivery activity of the copolymer nanocomposite were tested. The obtained results were analyzed and critically compared. C