2012
DOI: 10.3390/ijms13056279
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Synthesis and Characterization of Hybrid Materials Consisting of n-octadecyltriethoxysilane by Using n-Hexadecylamine as Surfactant and Q0 and T0 Cross-Linkers

Abstract: Novel hybrid xerogel materials were synthesized by a sol-gel procedure. n-octadecyltriethoxysilane was co-condensed with and without different cross-linkers using Q0 and T0 mono-functionalized organosilanes in the presence of n-hexadecylamine with different hydroxyl silica functional groups at the surface. These polymer networks have shown new properties, for example, a high degree of cross-linking and hydrolysis. Two different synthesis steps were carried out: simple self-assembly followed by sol-gel transiti… Show more

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Cited by 5 publications
(3 citation statements)
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“…[58] Hybrid materials differ from composite materials since they coexist in one single-phase and are integrated at the nanoscale. [59] Contrarily, composites exhibit a multiphase nature, where one phase, known as the filler, is dispersed in the other, called matrix. [60] Another way of classifying materials respects their dimension.…”
Section: Functional Materials For Olaementioning
confidence: 99%
“…[58] Hybrid materials differ from composite materials since they coexist in one single-phase and are integrated at the nanoscale. [59] Contrarily, composites exhibit a multiphase nature, where one phase, known as the filler, is dispersed in the other, called matrix. [60] Another way of classifying materials respects their dimension.…”
Section: Functional Materials For Olaementioning
confidence: 99%
“…While the following century gave birth to a whole new pantheon of medicinallyimportant inorganic compounds, the biggest impact in this area came from the serendipitous observation that a small platinum complex, cisplatin (cis-[PtCl2(NH3)2]), displayed potent antitumor properties in various cancer models [3][4][5][6][7]. Since this remarkable discovery, cisplatin and related platinum-based complexes are currently used world-wide for the treatment of testicular and ovarian malignancies.…”
Section: Introductionmentioning
confidence: 99%
“…Transition metal complexes exhibit a well-defined coordination geometries and distinct electrochemical or photophysical properties, thereby increasing the functionality of the binding agent. Redox-active metals generally form reactive oxygen species (ROS) and this ROS can be used to induce DNA cleavage [6][7][8]. The more donor atoms by which a molecule is bound to a metal ion, the stronger will be the assembly.…”
Section: Introductionmentioning
confidence: 99%