2024
DOI: 10.1021/acs.orglett.4c03442
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Synthesis and Characterization of Asymmetric Azatwistarenes with Chiroptical Property

Yanjie Zhu,
Guofeng Chen,
Yanjun Deng
et al.

Abstract: Three novel azatwistarenes 5a, 8, and 13 have been synthesized via the Povarov reaction and fully characterized. All of the enantiomers were separated using chiral high-performance liquid chromatography, and their optical properties were investigated through circular dichroism and circularly polarized luminescence spectra. In addition, such desired azatwistarenes have a positive response to acid in dichloromethane.

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