Synthesis and characterization of a new isoxazolone-based nonlinear optical crystal: MPMOI

Abstract

A new 3-(4-methoxy)-phenyl-5-isoxazolone-based MPMOI (C18H15NO4) crystal was designed and synthesized by the substitution of -OCH3 groups on the two sides of the molecular framework. Striped yellow MPMOI crystals were successfully...

Solvent-free synthesis and optical properties of two open-framework metal oxalates with zeolitic ABW and diamondoid topologies

“…Second-order nonlinear optical (NLO) crystals are important optoelectronic materials that have practical applications in laser science and technology. 5 It has been illustrated that π-conjugated oxoanions ( e.g. , BO 3 3− , CO 3 2− , and NO 3 − ) are ideal framework building blocks for NLO materials due to their relatively large microscopic second-order susceptibilities.…”