Synthesis and characterization of a Schiff base derived from 2-aminobenzylamine and its Cu(II) complex: electropolymerization of the complex on a platinum electrode

Demetgül, Cahıt; Deletioğlu, Didem; Karaca, Fılız; Yalçınkaya, Süleyman; Tımur, Mahir; Serın, Selahattın

doi:10.1080/00958972.2010.496852

Cited by 15 publications

(1 citation statement)

References 30 publications

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“…Zinc complexes of bidentate Schiff-base ligands have recently become popular in several disciplines of research due to their potential uses in biomolecules, catalysts, and optoelectronics [5][6]. There was also a study on the synthesis of numerous salicylaldehydes and benzylamine derivatives Schiff base from simple condensation and their complex [7][8][9][10]. Nanoparticles have gotten a lot of interest lately because of their wide range of uses, such as photocatalysis [11].…”

Section: ■ Introductionmentioning

confidence: 99%

Synthesis and Characterization of ZnO Nanoparticles via Thermal Decomposition for Zn(II) Schiff Base Complex

2022

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Zinc(II) oxide (ZnO) nanoparticles were easily produced in this research by thermal decomposition of the Zn(II) Schiff base complex. The ligand was synthesized via condensation of benzylamine with 2-hydroxybenzaldehyde. The Zn(II) Schiff base complex was prepared by the reaction between zinc salt and Schiff base with the molar ratio of 1:1 (metal:ligand). The binary complex powder was calcined at 700 °C to produce ZnO nanoparticles. Various methods were used to characterize the Schiff base, complexes, and nanoparticles, including 1H and 13C-NMR, FTIR, TGA, DTA thermal analysis, XRD, TEM, SEM, EDX, BET, UV-Vis Diffuse Reflectance, atomic absorption, melting point, and UV-Vis spectrophotometer. ZnO nanoparticles had an average crystallite size of 48.2 nm.

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Section: ■ Introductionmentioning

confidence: 99%

Synthesis and Characterization of ZnO Nanoparticles via Thermal Decomposition for Zn(II) Schiff Base Complex

2022

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Metal‐containing Polymers via Electropolymerization

et al. 2011

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Electropolymerization represents a suitable and well-established approach for the assembly of polymer structures, in particular with regard to the formation of thin, insoluble films. Utilization of monomers that are functionalized with metal complex units allows the combination of structural and functional benefits of polymers and metal moieties. Since a broad range of both electropolymerizable monomers and metal complexes are available, various structures and, thus, applications are possible. Recent developments in the field of synthesis and potential applications of metal-functionalized polymers obtained via electropolymerization are presented, highlighting the significant advances in this field of research.

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Electrocatalytic Investigations of Cu(II) and Fe(III) Complexes of Salophen Derivative Schiff Bases on the Pencil Graphite Electrode

2020

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This present study describes a pencil graphite electrode surface covered with Cu(II) and Fe(III) complexes based on Salophen derivative Schiff bases in acetonitrile solution containing LiClO4 as a supporting electrolyte. Cyclic voltammetry method was used for the surface modification procedure with 25 cycle at a sweep rate of 50 mV s−1. Some characterization methods were used to identify of the prepared modified surfaces including cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), Ultraviolet‐visible Spectroscopy (UV‐Vis), and Scanning Electron Microscopy/Energy Dispersive X‐ray Spectroscopy (SEM/SEM‐EDX). The catalytic activity of these modified surfaces on the electrochemical oxidation of catechol (CC) was investigated and they compared with each other. The results demonstrated that these modified electrodes showed perfect electrocatalytic activity on the catechol determination, however the modified electrode prepared with the Cu(II) complex has higher catalytic activity than this prepared with the Fe(III) complex thanks to its the lower detection limit.

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Synthesis and characterization of a Schiff base derived from 2-aminobenzylamine and its Cu(II) complex: electropolymerization of the complex on a platinum electrode

Cited by 15 publications

References 30 publications

Synthesis and Characterization of ZnO Nanoparticles via Thermal Decomposition for Zn(II) Schiff Base Complex

Synthesis and Characterization of ZnO Nanoparticles via Thermal Decomposition for Zn(II) Schiff Base Complex

Metal‐containing Polymers via Electropolymerization

Electrocatalytic Investigations of Cu(II) and Fe(III) Complexes of Salophen Derivative Schiff Bases on the Pencil Graphite Electrode

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