Synthesis and characterisation of transition-metal-substituted gallium phosphates with the laumontite structure

Open-Framework Inorganic Materials

“…The laumontite structure type has also been obtained with iron or manganese replacing cobalt atoms in the framework. [109] By contrast, CoGaPO-5 (CGF) [110] exhibits a novel framework topology based on alternating [PO 4 ] and [MO 4 ] (M Ga, Co) tetrahedra. It consists of two sets of channels delimited by 8-and 10-rings perpendicular to 8-ring channels, similar to the system encountered in heulandite.…”

Syntheses and Structures of Two Ammonium Zinc Gallophosphates: Analcime and Paracelsian analogs

“…Zn/Ga}O(1) 1.923(4) P(1)}O (1) 1.539(4) Zn/Ga}O (2) 1.900(4) P(1)}O (2) 1.541(4) Zn/Ga}O (3) 1.877(5) P(1)}O (3) 1.520(5) Zn/Ga}O (4) 1.883 (5) P (1)}O (4) 1.524(5) N(1)2O (1) 2.919(8) N(2)2O (2) 2.827(7) N(1)2H (11)2O(1) 162.4(3) N(2)2H (21)2O (2) 166.2(3) N(1)2O (3) 3.143 (8) N (2)2O (4) 3.343(8) N(1)2H (12)2O(3) 127.4(4) N(2)2H (22) (2) 1.873(3) P(1)}O (3) 1.531(2) Zn(1)/Ga(1)}O(4) 1.875(2) P(1)}O (5) 1.530(3) Zn(1)/Ga(1)}O(6) 1.879(2) P(1)}O (7) 1.525(3) Zn(1)/Ga(1)}O (7) 1.861(2) P(2)}O (2) 1.526(3) Zn(2)/Ga(2)}O(1) 1.879(2) P(2)}O (8) 1.526(2) Zn(2)/Ga(2)}O (8) 1.885(2) P(2)}O (4) 1.529(3) Zn(2)/Ga(2)}O(3) 1.884(2) P(2)}O (6) 1.526(3) Zn(2)/Ga(2)}O (5) 1.861(2) N2O (1) 2.977(4) N2O(4) 2.872(4) N2O (2) 3.037(5) N2O (5) 2.888(5) N2O (3) 2.965(4) N2O(6) 2.906(5) N2O (8) 2.946 (5) and selected bond and contact distances in Table 6. Further details of crystal structure investigation are available from the authors.…”

Anorganische Materialien mit offenen Gerüsten

“…Der Laumontit-Strukturtyp wurde auch mit Eisen oder Mangan anstelle der Cobaltatome erhalten. [109] Dagegen weist CoGaPO-5 (CGF) [110] eine neuartige Gerüsttopologie auf, die auf alternierenden [PO 4 ]-und [MO 4 ]-Tetraedern (M Ga, Co) beruht. Es besteht aus zwei Sätzen von Kanälen, die von Achter-bzw.…”