Abstract:The novel ruthenium(II) complexes containing 5-(pyridin-4-yl)-1,3,4-thiadiazol-2-amine(1) and 4-amino-5-(pyridin-4-yl)-4H-1,2,4-triazole-3-thiol (2) ligands were synthesized and characterized by UV-Vis, IR, NMR, and elemental analysis. The complexes have been employed as catalysts for the transfer hydrogenation of acetophenone in the presence of KOH using 2-propanol as a hydrogen source at 82 • C. Moreover, the temperature dependence of conductivity of the complexes was determined in the temperature range of 3… Show more
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