Synthesis and catalytic activities of two new extended Preyssler–type tungstophosphates with different cavity centers

Du, Jing; Cao, Mei-Da; Zhu, Zai‐Ming; Su, Fang; Zhang, Lancui

doi:10.1016/j.inoche.2016.10.018

Cited by 4 publications

(2 citation statements)

References 34 publications

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“…In recent years, our group hass uccessfully synthesized as eries of 3D POM-based inorganic-organic hybrid materials with TM-H 2 biim complexes through ah ydrothermalm ethod. [27][28][29][30] These materials revealed salient catalytic properties and structural stabilities. However, it is still ag reat challenge to construct high-dimensional coordination polymers by using large POM buildingb locks.…”

Section: Synthesismentioning

confidence: 99%

“…The weak bands in the region of ñ = 1631-1411cm À1 can be assignedt oi midazole ring stretching. [27,28] To verify the purity of the products, the PXRD patterns of compounds 1 and 2 were recorded ( Figure S9 in the Supporting Information) and the simulated patterns of compounds 1 and 2 were calculated from the CIF file by using Mercury software (Copyright Cambridge Crystallographic Data Centre). As seen from Figure S9 25.87 (425), and 27.628 (048);t hese results indicated that compounds 1 and 2 were isostructural.…”

Section: Characterizationo Fc Ompounds 1a Ndmentioning

confidence: 99%

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Two New Preyssler‐Type Polyoxometalate‐Based Coordination Polymers and Their Application in Horseradish Peroxidase Immobilization

Cao

Feng

et al. 2017

Chemistry A European J

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Enzyme immobilization is of increasing importance for biocatalysis, for which good supports are critical. Herein, two new Preyssler-type polyoxometalate (POM)-based coordination polymers, namely, {[Cu(H biim) ][{Cu(H biim) (μ-H O)} Cu(H biim)(H O) ]H[({Cu(H biim)(H O) } ) ((μ-C HN Cl ){Cu(H biim)} ){Z(H O)P W O }]⋅x H O} (1: Z=Na, x=9; 2: Z=Ag, x=10; H biim=2,2'-biimidazole) were designed and synthesized. Compounds 1 and 2 exhibit the same skeletons, which contain multiple Cu complex fragments and penta-supported {ZP W } (Z=Na, Ag) clusters. They were first employed to immobilize horseradish peroxidase (HRP). Results show that compounds 1 and 2 are good supports for HRP immobilization, and exhibit higher enzyme loading, lower loading times, and excellent reusability. The immobilized HRP (HRP/1 or HRP/2) was further applied to detect H O , and good sensitivity, wide linear range, low detection limit, and fast response were achieved. This work shows that POM-based hybrid materials are a new kind of promising support for enzyme immobilization.

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Section: Synthesismentioning

confidence: 99%

Section: Characterizationo Fc Ompounds 1a Ndmentioning

confidence: 99%

Two New Preyssler‐Type Polyoxometalate‐Based Coordination Polymers and Their Application in Horseradish Peroxidase Immobilization

Cao

Feng

et al. 2017

Chemistry A European J

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Preyssler-type polyoxometalate-based crystalline materials for the electrochemical detection of H₂O₂

Zhu

Tang

et al. 2021

CrystEngComm

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TEMPO coordination and reactivity in group 6; pseudo-pentagonal planar (η²-TEMPO)₂CrX (X = Cl, TEMPO)

et al. 2022

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Synthesis and catalytic activities of two new extended Preyssler–type tungstophosphates with different cavity centers

Cited by 4 publications

References 34 publications

Two New Preyssler‐Type Polyoxometalate‐Based Coordination Polymers and Their Application in Horseradish Peroxidase Immobilization

Two New Preyssler‐Type Polyoxometalate‐Based Coordination Polymers and Their Application in Horseradish Peroxidase Immobilization

Preyssler-type polyoxometalate-based crystalline materials for the electrochemical detection of H₂O₂

TEMPO coordination and reactivity in group 6; pseudo-pentagonal planar (η²-TEMPO)₂CrX (X = Cl, TEMPO)

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Synthesis and catalytic activities of two new extended Preyssler–type tungstophosphates with different cavity centers

Cited by 4 publications

References 34 publications

Two New Preyssler‐Type Polyoxometalate‐Based Coordination Polymers and Their Application in Horseradish Peroxidase Immobilization

Two New Preyssler‐Type Polyoxometalate‐Based Coordination Polymers and Their Application in Horseradish Peroxidase Immobilization

Preyssler-type polyoxometalate-based crystalline materials for the electrochemical detection of H2O2

TEMPO coordination and reactivity in group 6; pseudo-pentagonal planar (η2-TEMPO)2CrX (X = Cl, TEMPO)

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Preyssler-type polyoxometalate-based crystalline materials for the electrochemical detection of H₂O₂

TEMPO coordination and reactivity in group 6; pseudo-pentagonal planar (η²-TEMPO)₂CrX (X = Cl, TEMPO)