Synthesis and applications of metal-organic frameworks and graphene-based composites: A review

Adsorptive Desulfurization of Liquid Hydrocarbons Utilizing Granular Cu/Cr-BDC@γ-Al2O3 Bimetal-Organic Frameworks

“…However, in powder adsorbents, it was necessary to centrifuge the solution. Also, the regeneration of the granular forms of adsorbent was much easier. ,, Finally, granulation can be considered an important step toward the industrialization of the adsorbent. Granules in addition to increasing the chemical and mechanical stability of adsorbents can be used in the fixed-bed and packed-bed forms, and due to the high flow rate in the refining industries, the batch method is not appropriate.…”

Removal of Toxic Pollutants from Industrial Effluent: Sustainable Approach and Recent Advances in Metal Organic Framework

“…Of these conventional techniques, solvothermal and nonsolvothermal are commonly used, because of their ease of operation. 53,54 Water is utilized as the solvent in hydrothermal techniques that are inexpensive, simple, safe, and effective methods for synthesizing MOFs. Figure 1 shows the synthesis of MOFs.…”

“…Various commercial methods are available for synthesis of MOFs such as ion synthesis, solvothermal and nonsolvothermal, microwave, electrochemical and diffusion. Of these conventional techniques, solvothermal and nonsolvothermal are commonly used, because of their ease of operation. , Water is utilized as the solvent in hydrothermal techniques that are inexpensive, simple, safe, and effective methods for synthesizing MOFs. Figure shows the synthesis of MOFs.…”

Three-dimensional graphene/metal–organic framework composites for electrochemical energy storage and conversion

“…[32][33][34][35][36] 3DG/MOF composites and their derivatives can integrate the advantages of their constituent materials, which can not only improve the electrical conductivity and stability of MOFs, but also the structure of MOFs can be optimized through bonding and/or strengthening coordination bonds due to the abundant functional groups of graphenebased materials. [37][38][39] In addition, 3DG sheets are stable in the existence of MOFs, exposing a larger specific surface area and more active sites. The hierarchical porous structure formed in 3DG/MOF composites is conducive to electrolyte entry and mass transfer resistance reduction, and the close contact between 3DG sheets and MOFs can enhance the adsorption energy and ion transport mechanics, so as to achieve excellent energy storage performance.…”