Synthesis and Antioxidant Investigation of Ag&lt;sub&gt;2&lt;/sub&gt;S Nanoparticles Obtained from Silver(I) Complex of &lt;i&gt;N&lt;/i&gt;-Methyl&lt;i&gt;-N&lt;/i&gt;-Phenyl- Dithiocarbamate

Ajiboye, Timothy O.; Onwudiwe, Damian C.

doi:10.4028/p-f5c470

Cited by 4 publications

(2 citation statements)

References 45 publications

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“…Compound (12) displayed the best radical scavenging activity, with a value of (19.10) μg/ml, surpassing other compounds in comparison to ascorbic acid, which had a value of (39.16) μg/ml. Additionally, several other complexes (2, 4, 7, 11, 15, 16, 18, 19 & 20) exhibited notable activity with values ranging from (35.95) μg/ml to (38.76) μg/ml, again when compared to ascorbic acid (39.16) μg/ml (Ajiboye & Onwudiwe, 2022) and (Andotra et al, 2017).…”

Section: Biological Activity 1 Antioxidant Activitymentioning

confidence: 98%

Synthesis, Characterization, Dft, and Biological Assay of New Xanthate Complexes With Nitrogen Bases

Molla-Babaker,

Khalid,

AL-Mukhtar

2024

SJUOZ

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This study introduces a new series of complexes and adducts, denoted by [M(2-PhOEtXant)2.nL], where M represents Mn(II), Fe(II), Co(II), or Ni(II), and the ligand (2-PhOEtXant) is 2-Phenoxyethylxanthate. Varying ligands, including pyridine, piperidine, quinoline, ethylenediamine, and (1,10)-phenanthroline, are explored based on the value of n. Comprehensive characterization, encompassing techniques like 1H-NMR, 13C-NMR, FTIR, AA, CHN analysis, UV-visible spectroscopy, and magnetic property measurements, is employed. Results indicate an octahedral geometry for these complexes, as revealed by effective magnetic moment measurements and electronic spectra analysis. The compounds exhibit noteworthy antioxidant properties, demonstrated through the DPPH radical scavenging method, highlighting their potential as effective antioxidants. Moreover, the complexes display enhanced antibacterial activity against microbial strains compared to free ligands. This research not only delves into the coordination chemistry of these complexes but also underscores their diverse applications. Combining experimental methods with computational insights using Density Functional Theory (DFT) enhances the understanding of dithiolate transition metal complexes. The alignment of computational and experimental outcomes strengthens the reliability of the findings, laying a robust foundation for interdisciplinary exploration. The identified potential applications in optoelectronics, along with the notable antioxidant and antibacterial activities, position these complexes as promising contenders for advanced technologies and scientific applications.

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Section: Biological Activity 1 Antioxidant Activitymentioning

confidence: 98%

Synthesis, Characterization, Dft, and Biological Assay of New Xanthate Complexes With Nitrogen Bases

Molla-Babaker,

Khalid,

AL-Mukhtar

2024

SJUOZ

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“…Khirid et al fabricated silver sulfide nanowire using [(PPh3)2AgS2P(OiPr)2] single precursor in the presence of a mixture of amines for catalytic application in hydrogen evolution reaction [85]. In a more recent study, Ag(I) complex of N-methyl-N-phenyl dithiocarbamate has been used as a single source precursor to obtain oleylamine capped monoclinic Ag 2 S nanoparticles at 180°C [86]. Khan and coworkers described single molecular precursor method for the synthesis of silver-based metallic, intermetallic, and metal sulfide nanoparticles using xanthate precursors.…”

Section: Synthesis Using Decomposition Of Single Molecular Precursorsmentioning

confidence: 99%

Synthesis and Photocatalytic Applications of Silver Sulfide Nanostructures: Recent Advancement

Kumar,

Shekhar,

Arora

et al. 2024

Smart Nanosystems - Advances in Research and Practice [Working Title]

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Silver sulfide nanoparticles belong to the family of important metal chalcogenides. Silver sulfide has been extensively studied in recent years due to its applications in various fields ranging from biosensors, infrared detectors, and optoelectronics to catalysis. Silver sulfide is considered as a potential photocatalyst due to narrow band gap energy, mechanical and thermal stability, cyclability, and ease of synthesis. Different methods have been investigated to produce various forms of silver sulfide nanoparticles. The present chapter focuses on the recent progress in synthesis of silver sulfide nanoparticles using hydrothermal method, chemical bath deposition, microwave-based approach, sonochemical method, single molecular precursor’s decomposition, and green synthesis. Moreover, the application of silver sulfide nanoparticles in photocatalytic degradation of organic dyes is discussed in details.

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Review on synthesis method, biomolecules involved, size affecting factors and potential applications of silver nanoparticles

Githala,

Trivedi

2023

Biocatalysis and Agricultural Biotechnology

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Synthesis and Antioxidant Investigation of Ag<sub>2</sub>S Nanoparticles Obtained from Silver(I) Complex of <i>N</i>-Methyl<i>-N</i>-Phenyl- Dithiocarbamate

Cited by 4 publications

References 45 publications

Synthesis, Characterization, Dft, and Biological Assay of New Xanthate Complexes With Nitrogen Bases

Synthesis, Characterization, Dft, and Biological Assay of New Xanthate Complexes With Nitrogen Bases

Synthesis and Photocatalytic Applications of Silver Sulfide Nanostructures: Recent Advancement

Review on synthesis method, biomolecules involved, size affecting factors and potential applications of silver nanoparticles

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