Syntheses, structures, photoelectric properties and photocatalysis of iodobismuthate hybrids with lanthanide complex cations

Abstract

New iodobismuthate hybrids with lanthanide complex counter cations, [Ln(DMF)8][Bi2I9] (Ln = La (1), Eu (2)) and [Tb(DMF)8]2[Bi2I9]2 (3) (DMF = N,N-dimethylformamide), were prepared using solvated Ln(III) complexes formed in situ...