Syntheses, Structures, and Properties of Mono- and Dinuclear Acetylacetonato Ruthenium(III) Complexes with Chlorido or Thiocyanato Ligands
Kai Nakashima,
Chihiro Hayami,
Shino Nakashima
et al.
Abstract:The mononuclear and dinuclear ruthenium(III) complexes trans-Ph4P[RuIII(acac)2Cl2] (1), Ph4P[{RuIII(acac)Cl}2(μ-Cl)3] (2) and trans-Ph4P[RuIII(acac)2(NCS)2]·0.5C6H14 (3·0.5C6H14) were synthesized. Single crystals of 1, 2·H2O and 3·CH3CN suitable for X-ray crystal structure analyses were obtained through recrystallization from DMF for 1 and 2·H2O and from acetonitrile for 3·CH3CN. An octahedral Ru with bis-chelate-acac ligands and axial chlorido or κ-N-thiocyanido ligands (for 1 and 3·CH3CN) and triply µ-chlori… Show more
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