Syntheses of (exo- and endo-dialkylphosphonate-η5-cyclohexadienyl)mangenese tricarbonyl compounds

Bae, Hye Kyung; Jung, Il Nam; Chung, Young Keun

doi:10.1016/s0022-328x(00)99351-3

Cited by 7 publications

References 10 publications

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Cationic (η⁶‐arene)‐ and Neutral (η⁵‐cyclohexadienyl)‐tricarbonylmanganese Complexes: Synthesis and Reactivity

Rose‐Munch

Rose

Eloi

2010

Patai's Chemistry of Functional Groups

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The tricarbonyl‐chromium and ‐manganese groups are known to easily coordinate arene rings to form η 6 ‐arene complexes. The electrophilic nature of the tricarbonyl metal fragments makes the arene electron‐deficient and renders it susceptible to nucleophilic attack. It is for these reasons that a new trend has emerged, the study of the chemistry of (η 5 ‐cyclohexadienyl)Mn(CO) 3 complexes which are easily obtained by addition of a nucleophile to the arene ring. In the last ten years, the discovery of new methods of functionalization involving Pd cross‐coupling and lithiation reactions has greatly expanded the scope of the (η 5 ‐cyclohexadienyl)Mn(CO) 3 complexes and consequently represents a key step in the development of the arene manganese chemistry since [(η 6 ‐arene)Mn(CO) 3 ] + complexes can be easily obtained by rearomatization of the corresponding (η 5 ‐cyclohexadienyl)Mn derivatives. The present review aims to describe the situation for the synthesis and the reactivity of η 6 ‐arene‐Mn complexes as well as that of η 5 ‐cyclohexadienyl‐Mn complexes to highlight the recent breakthrough in their chemistry. The main reactivities described for η 5 Mn complexes correspond to nucleophilic addition, lithiation/electrophilic quench, lithium/halogen exchange and Pd catalyzed reactions. These types of reactions can be efficiently compared with those well studied in η 6 arenetricarbonylchromium complexes. All these recent developments in the functionalization of η 5 ‐ and η 6 ‐Mn complexes described in this chapter clearly open a revival period for this type of complexes which are starting to emerge as a valuable and versatile class of compounds more environmentally friendly than their Cr analogs.

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Cationic (η⁶‐arene)‐ and Neutral (η⁵‐cyclohexadienyl)‐tricarbonylmanganese Complexes: Synthesis and Reactivity

Rose‐Munch

Rose

Eloi

2010

Patai's Chemistry of Functional Groups

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Crystal and molecular structures of [{exo- and endo-(RO)2P(O)-η5-C6H6}Mn(CO)3]

Lee

Hye-kyung

Young

et al. 1994

Inorganica Chimica Acta

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Selected reactions of transition metal π-complexes annual survey covering the year 1986

Rockett

Marr

1988

Journal of Organometallic Chemistry

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Syntheses of (exo- and endo-dialkylphosphonate-η5-cyclohexadienyl)mangenese tricarbonyl compounds

Cited by 7 publications

References 10 publications

Cationic (η⁶‐arene)‐ and Neutral (η⁵‐cyclohexadienyl)‐tricarbonylmanganese Complexes: Synthesis and Reactivity

Cationic (η⁶‐arene)‐ and Neutral (η⁵‐cyclohexadienyl)‐tricarbonylmanganese Complexes: Synthesis and Reactivity

Crystal and molecular structures of [{exo- and endo-(RO)2P(O)-η5-C6H6}Mn(CO)3]

Selected reactions of transition metal π-complexes annual survey covering the year 1986

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Syntheses of (exo- and endo-dialkylphosphonate-η5-cyclohexadienyl)mangenese tricarbonyl compounds

Cited by 7 publications

References 10 publications

Cationic (η6‐arene)‐ and Neutral (η5‐cyclohexadienyl)‐tricarbonylmanganese Complexes: Synthesis and Reactivity

Cationic (η6‐arene)‐ and Neutral (η5‐cyclohexadienyl)‐tricarbonylmanganese Complexes: Synthesis and Reactivity

Crystal and molecular structures of [{exo- and endo-(RO)2P(O)-η5-C6H6}Mn(CO)3]

Selected reactions of transition metal π-complexes annual survey covering the year 1986

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Cationic (η⁶‐arene)‐ and Neutral (η⁵‐cyclohexadienyl)‐tricarbonylmanganese Complexes: Synthesis and Reactivity

Cationic (η⁶‐arene)‐ and Neutral (η⁵‐cyclohexadienyl)‐tricarbonylmanganese Complexes: Synthesis and Reactivity