Abstract:Syntheses of Enantiopure 3,4-Diamino-1-substituted Pyrrolidines. -Key step of the described approach is the twofold substitution of dimesylates (III) with azide. Use of LiN3 instead of NaN3 permits the synthesis of diazides (IV) in satisfactory yields. -(MARSON*, C. M.; MELLING, R. C.; Synthesis 2006, 2, 247-256; Christopher Ingold Lab., Dep. Chem., Univ. Coll., London WC1H 0AJ, UK; Eng.) -M. Paetzel 22-112
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