Syntheses, Crystal Structures, and Photothermal Conversion Property of Aluminum Cluster Molecular Rings-Based Heterometallic Complexes
Wei Lv,
Song-Yan Sui,
Zhe Xue
et al.
Abstract:Effective combination of Al clusters
with functional motif is a
good way to expand the application of Al cluster materials. In this
work, by introducing noble-metal ions with photothermal property into
the assembly of aluminum clusters, four Al8-based mixed
metal complexes, {[Al8Ag2(OH)8(NA)16(CH3CN)2]·2SO3CF3}
n
(Ag–Al
8
, NA–
= nicotinic acid), {[(H3O)2Al8Ag3Cl9(OH)8(NA)2(HNA)14]·AgCl4·Ag2Cl7·2SO3CF3}
n
(AgCl-Al
8
), {[Al8Cu4Br3(OH)8(NA)16]·NA·HNA}
n
(CuBr-Al
8
-1) and {[Al8Cu4Br2(OH)8(NA)16]·2NA}
n
… Show more
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