Syntheses and Coordination Chemistry of Aminomethylphosphine Derivatives of Adenine

Gold(I) complex of 1,1′-bis(diphenylphosphino) ferrocene–quinoline conjugate: a virostatic agent against HIV-1

“…The geometry around gold is virtually linear and coordination sites are occupied by phosphorus and chloride atoms with P-Au-Cl bond ~175 which is normally observed for bicoordinated gold(I) complexes (Zhang et al 2003;Williams et al 2007;Fonteh et al 2015). …”

Phosphines and Related Tervalent Phosphorus Systems

“…411 Mannich reactions between hydroxymethylphosphines and amines have been applied in the synthesis of a variety of new aminomethylphosphines. Included among these are aminomethylphosphine derivatives of adenine, 412 the new unsymmetrical phosphine Ph 2 PCH 2 NHC 6 H 4 PPh 2 , 413 a polymer-bound (N-phosphinoethyl)-aminomethylphosphine, 414 and water-soluble aminomethyl(ferrocenylmethyl)-phosphines. 415 Bis(phosphinomethyl)amino systems have also been described, e.g., (166), 416 the amphiphilic and water-soluble systems (167), 417 and a bis(aminomethylphosphine) derived from 3,4-diaminotoluene.…”

Synthesis of platinum, palladium and rhodium complexes of α-aminophosphine ligands

“…The coordination of bis(diphenylphosphinomethyl)amino derivatives of adenine to transition metals was also investigated (Scheme 26). 65 A series of bidentate chelate complexes was synthesized in good yields using various Pt II and Pd II (cod) precursors. It was observed that all complexes retained the free adenine moiety for complementary hydrogen bonding.…”