Synthese von 2-Ethyliden-6-hepten-5-olid

Behr, Arno; Juszak, K.-D.; Keim, W.

doi:10.1055/s-1983-30432

Cited by 78 publications

(26 citation statements)

References 0 publications

Supporting

Mentioning

Contrasting

Unclassified

Order By: Relevance

“…These discoveries led to profound interest in the selective synthesis of the δ-lactone. Thus, several works from the laboratories of Behr [21,22,24], Dinjus [25,26], and Braunstein [27] were aimed at obtaining a deeper understanding of the operative mechanism for this and related coupling reactions in order to control the selectivities of these processes. These approaches have mainly remained focused on the application of bulky phosphine ligands.…”

Section: Reactions With Group 10 Metalsmentioning

confidence: 99%

Transition Metal-Catalyzed Carboxylation of Organic Substrates with Carbon Dioxide

Brill

Lazreg

Cazin

et al. 2015

Topics in Organometallic Chemistry

View full text Add to dashboard Cite

The development of sustainable chemical processes is a long-standing challenge. Carbon dioxide represents a renewable C1 building block for organic synthesis and industrial applications as an alternative to other common feedstocks which are based on natural gas, petroleum oil, or coal. Apart from the advantages associated with the nontoxicity and abundance of CO 2 , its utilization further enables the reduction in its atmospheric content, which contributes significantly to the greenhouse effect. Although widespread application of CO 2 in organic synthesis -even on an industrial scale -will not be able to fully compensate for the steadily increasing atmospheric quantities produced (mainly by the combustion of fuels), ecological and economical factors make its usage highly desirable. Therefore, tremendous efforts toward activation and utilization of CO 2 have been made by the scientific community over the last 30 years, and, as a result, the number of highly efficient transition metal-catalyzed CO 2 -incorporative reactions has increased dramatically, especially within the last decade. The achievements in the development of sustainable and economic chemical processes for the carboxylation of organic molecules with CO 2 are presented in detail in this chapter.

show abstract

Section: Reactions With Group 10 Metalsmentioning

confidence: 99%

Transition Metal-Catalyzed Carboxylation of Organic Substrates with Carbon Dioxide

Brill

Lazreg

Cazin

et al. 2015

Topics in Organometallic Chemistry

View full text Add to dashboard Cite

show abstract

“…[65] Sie fanden, dass die Basizität und der Kegelwinkel der eingesetzten Phosphane einen großen Einfluss auf die Produktverteilung haben. Mit voluminçsen Phosphanen werden Lactone bevorzugt, während kleinere Phosphane zu offenen Estern führen.…”

Section: Koordination Von Co 2 An üBergangsmetallkom-plexeunclassified

Umwandlung von Kohlendioxid mit Übergangsmetall‐Homogenkatalysatoren: eine molekulare Lösung für ein globales Problem?

et al. 2011

View full text Add to dashboard Cite

In der Vergangenheit wurde eine Vielzahl von Methoden zur Verwendung von Kohlendioxid in der organischen Synthese entwickelt. Trotz der breiten Gesamtverfügbarkeit von CO2 auf der Erde ist sein Einsatz als Reaktant, insbesondere in der Synthesechemie, recht selten. In den letzten 35 Jahren wurde intensiv daran geforscht, kosten‐ und energieeffiziente katalytische Prozesse zu finden, um CO2 zu Carbonsäuren, Estern, Lactonen und Polymeren umzusetzen. Dieser Aufsatz fasst die bis heute vorhandenen homogenkatalytischen Routen zur Verwendung von CO2 als C1‐Kohlenstoffquelle für die Synthese industrieller Produkte sowie Feinchemikalien zusammen.

show abstract

“…The product can be hydrogenated to 2-ethylheptanoic acid, which can be used in lubricants, as a stabilizer for PVC or as an intermediate for the production of solvents and softeners [7,[15][16][17][18][19].…”

Section: Telomerization Of Butadiene With Carbon Dioxidementioning

confidence: 99%

Multiphase Catalysis in Temperature-Dependent Multi-Component Solvent (TMS) Systems

Behr

Turkowski

Roll

et al. 2006

Regulated Systems for Multiphase Catalysis

View full text Add to dashboard Cite

Synthese von 2-Ethyliden-6-hepten-5-olid

Cited by 78 publications

References 0 publications

Transition Metal-Catalyzed Carboxylation of Organic Substrates with Carbon Dioxide

Transition Metal-Catalyzed Carboxylation of Organic Substrates with Carbon Dioxide

Umwandlung von Kohlendioxid mit Übergangsmetall‐Homogenkatalysatoren: eine molekulare Lösung für ein globales Problem?

Multiphase Catalysis in Temperature-Dependent Multi-Component Solvent (TMS) Systems

Contact Info

Product

Resources

About