Synthese und Struktur von [Li(thf)4]2‐[(Ph2P)10Cd4] ‐ ein dianionischer Komplex mit Cd4P10‐Adamantangerüst

The ion-separated complex 2[Li(thf) 4 ] ϩ [Mn(C 12 H 8 N) 4 ] 2Ϫ 1 has been obtained from the nucleophilic substitution reaction of [Mn{N(SiMe 3 ) 2 } 2 ]ؒ2thf with Li[C 12 H 8 N] (1 : 4 equivalents) (thf = tetrahydrofuran, C 12 H 8 N = carbazol-9-yl), and the molecular species [Mn(C 12 H 8 N) 2 ]ؒ3thf 2 from the acid-base reaction of [Mn{N(SiMe 3 ) 2 } 2 ]ؒ2thf and C 12 H 8 NH (1 : 2 equivalents). They are among the few amidomanganese() complexes containing simple (sterically undemanding) dialkyl-or diaryl-amido groups to be characterised. The crystal structures of both were determined: 1 contains the first tetraamidomanganese() dianion and 2 possesses the highest co-ordination number for Mn II in such a compound.

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Synthese und Struktur von [Li(thf)₄]₂‐[(Ph₂P)₁₀Cd₄] ‐ ein dianionischer Komplex mit Cd₄P₁₀‐Adamantangerüst

Cited by 5 publications

References 19 publications

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Nucleophilic substitution vs. acid–base reactions of [Mn{N(SiMe3)2}2]·2thf; syntheses and structures of 2[Li(thf )4]+[Mn(C12H 8N)4]2−·C6 H5Me and [Mn(C12H8N)2]·3thf (thf = tetrahydrofuran, C12H8N = carbazol-9-yl)

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