Synthese und struktur eines rhenium-zweikernkomplexes mit einem λ3-diazadiphosphetidin als brückenligand

Scherer, Otto J.; Anselmann, Ralf; Sheldrick, William S.

doi:10.1016/s0022-328x(00)99193-9

Cited by 17 publications

(2 citation statements)

References 12 publications

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“…For several years, the coordination chemistry of cyclodiphosphazanes was restricted to a limited exploration of chloro-, fluoro-and a few alkoxy and aryloxy derivatives with group 6 metal carbonyls and a few late transition metal derivatives. 20 Rhodium, palladium and platinum complexes of fluoro-and chlorocyclodiphosphazanes isolated by Nixon's group [69][70][71] as well as others 72…”

Section: Transition Metal Chemistry Of Cyclodiphosphazanesmentioning

confidence: 99%

Cyclodiphosphazanes: options are endless

Balakrishna

2016

Dalton Trans.

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Cyclodiphosphazanes, also known as diazadiphosphetidines, are saturated inorganic ring systems containing alternating trivalent phosphorus and nitrogen atoms. With a rigid planar structure and moderately stable P-N bonds, cyclodiphosphazanes have shown versatility not only in coordination chemistry as both neutral and anionic ligands but also as useful scaffolds in supramolecular chemistry, resulting in a plethora of molecules with interesting structural features. Recent reports on their utility in generating several 3D-coordination polymers including those with sodalite structures, cyclodiphosphazane based N-heterocyclic carbenes and stable biradicaloids highlight the versatility of these novel phosphorus-nitrogen cyclic compounds. This review describes mainly the coordination chemistry of cyclodiphosphazanes as neutral ligands and their applications besides recent advances in cyclodiphosph(iii)azane chemistry. The key points on the empirical model proposed to highlight the coordinating ability of cyclodiphosphazanes to build soft-soft MOFs and an analysis of pertinent structural features are also presented.

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Section: Transition Metal Chemistry Of Cyclodiphosphazanesmentioning

confidence: 99%

Cyclodiphosphazanes: options are endless

Balakrishna

2016

Dalton Trans.

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“…condensation of chlorophosphanes with primary amines or their silylated derivatives) that lead to the acylic diphosphazanes(l) (Keat 1982(Keat , 1987. The coordination chemistry of cyclodiphosphazanes(lI) has been investigated only to a limited extent as compared to that of the acyclic diphosphazanes(l) (Burckett St. Laurent et al 1983;Scherer et al 1984). Bicyclic diphosphazanes(Ill, R = Bu t) were first reported by Keat and Thompson (1977).…”

Section: Introductionmentioning

confidence: 99%

Organometallic chemistry of diphosphazane ligands

Krishnamurthy

1990

Proc. Indian Acad. Sci. (Chem. Sci.)

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The reactions of a range of acyclic, cyclic and bicyclic diphosphazanes with several transition metal organometallic derivatives have been investigated. The structures of the products have been deduced from IR and NMR spectroscopic data and confirmed by single crystal X-ray analysis of a few representative compounds. Keywords. Diphosphazane ligands; group 6, iron carbonyl and Pd, Pt and Rh complexes.

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