Synthese und Charakterisierung von Polyestern und Polyamiden auf der Basis von Furan‐2,5‐dicarbonsäure

Fehrenbacher, Ulrich; Grosshardt, Otto; Kowollik, K.; Tübke, Beatrice; Dingenouts, N.; Wilhelm, M.

doi:10.1002/cite.200900090

Cited by 63 publications

(27 citation statements)

References 9 publications

(3 reference statements)

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The TGA analysis revealed a T d of approximately 405°C (. against the 350°C reported previously by Grosshardt et al 54 ). In the same patents Gruter et al also reported the use of TPA and isophthalic acid dichlorides as linkers in conjunction with various PA-6F oligomers; the resulting PA-6FT and PA-6FI copolyamides were obtained with molar ratios of furanic / terephthalic (F / T) and furanic / isophthalic (F / I) units ranging from 80/20 to 25/75.…”

Section: Scheme 13supporting

confidence: 73%

“…All these attractive features have definitely motivated some studies about furanic polyamides through the years (see e.g. references 51,52,54,[148][149][150][151][152][153][154][155][156][157][158], including those dedicated to furanic -aliphatic and furanic -aromatic polyamides. Despite the enormous potential of this family of polymers, which are real biobased alternatives to existing petrochemical polyamides, recent literature dealing with FDCA is scarce, 51,52,54 with most published studies dating back from decades ago.…”

Section: Other Renewable Furanic Polycondensatesmentioning

confidence: 99%

“…references 51,52,54,[148][149][150][151][152][153][154][155][156][157][158], including those dedicated to furanic -aliphatic and furanic -aromatic polyamides. Despite the enormous potential of this family of polymers, which are real biobased alternatives to existing petrochemical polyamides, recent literature dealing with FDCA is scarce, 51,52,54 with most published studies dating back from decades ago. [148][149][150]152,153,[155][156][157][158][159][160] There are, however, noticeable recent achievements envisaging a fruitful future 161 which will be the focus of the present section.…”

Section: Other Renewable Furanic Polycondensatesmentioning

confidence: 99%

“…Recently they have been prepared using aliphatic diamines, ranging from C3 to C12. [51][52][53][54] Noticeable, the poly(hexamethylene 2,5-furandicarboxamide), among others, has been successfully prepared as described in a patented process after several reported problems associated with its synthesis. 51,52 Indeed, completely new strategies had to be developed for their preparation.…”

Section: Introductionmentioning

confidence: 99%

See 3 more Smart Citations

Biobased polyesters and other polymers from 2,5-furandicarboxylic acid: a tribute to furan excellency

et al. 2015

View full text Add to dashboard Cite

Motivated by a general concern on sustainability and environmental issues, a sparkling search for renewable-based polymers has grown exponentially in recent years. This search definitely spotlighted polyesters derived from 2,5-furandicarboxylic acid, among other polymers, as some of the most promising, especially due to the resemblance of this renewable monomer to the well-known petroleum-based terephthalic acid, as well as for the possibility of preparing innovative materials. The huge number of recent papers and patents about this family of polymers explore aspects such diverse as synthesis with other renewable-based monomers, leading to the preparation of materials with enhanced thermo-mechanical, biodegradability and liquid crystalline properties, among other features. Additional aspects pursued in such studies are innovation in the synthetic approaches or its optimisation; and also the development of applications for everyday-life objects like for example packaging materials, especially bottles, textiles, coating, toners, among many other uses. Despite this intense activity little has been reviewed recently about this unique family of polyesters, or derived polymers, as the only reviews on the subject date-back from the last century. In this perspective, the present appraisal aims at contributing to fulfil this literature gap, covering recent aspects related with challenges of developing polyesters, polyamides, or other polymers from 2,5-furandicarboxylic acid and their precursors. Emphasis is placed on monomer synthesis, polymerisation reactions, catalysts and applications.A tribute to 2,5-furandicarboxylic acid excellency and the myriad of novel polyesters, but also polyamides, among other polycondensates, is comprehensively done.

show abstract

Section: Scheme 13supporting

confidence: 73%

Section: Other Renewable Furanic Polycondensatesmentioning

confidence: 99%

Section: Other Renewable Furanic Polycondensatesmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 2 more Smart Citations

Biobased polyesters and other polymers from 2,5-furandicarboxylic acid: a tribute to furan excellency

et al. 2015

View full text Add to dashboard Cite

show abstract

“…A few pioneering papers have reported the synthesis of PA from FDCA and aliphatic diamine, but the early investigations did not pursue the details related to the polymer properties. Later, Grosshardt et al . synthesized various kinds of PA by reacting FDCA with the alkane diamines of C 6 –C 12 .…”

Section: Introductionmentioning

confidence: 99%

Solid‐state polymerization and characterization of a copolyamide based on adipic acid, 1,4‐butanediamine, and 2,5‐furandicarboxylic acid

Endah

Han

Kim

et al. 2016

J of Applied Polymer Sci

View full text Add to dashboard Cite

2,5‐Furandicarboxylic acid (FDCA) is a promising biobased alternative material to terephthalic acid. In this study, three types of poly(butylene adipamide) (PA‐4,6) containing 10, 20, and 30 mol % of poly(butylene‐2,5‐furandicarboxylamide) (PA‐4,F) were synthesized through consecutive prepolymerization and solid‐state polymerization (SSP). The incorporation of a 10 mol % PA‐4,F component into PA‐4,6 resulted in slight increases in the intrinsic viscosity (IV) and glass‐transition temperature (Tg) after 12 h of SSP at 220 °C. When the SSP temperature and reaction time increased, IV increased proportionally. The highest IV value of 0.75 was obtained by 48 h of SSP at 240 °C, whereas increases in the PA‐4,F content to 20 and 30 mol % gave rise to decreases in IV, Tg, and melting temperature; this interrupted the increase in SSP temperature. The thermal decomposition temperature of the PA‐4,F‐incorporated polyamide was lower than that with PA‐4,6 because of the lower thermal stability of the FDCA component. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43391.

show abstract

Polyesters, Polycarbonates and Polyamides Based on Renewable Resources

Noordover¹

2011

Renewable Polymers

View full text Add to dashboard Cite

Synthese und Charakterisierung von Polyestern und Polyamiden auf der Basis von Furan‐2,5‐dicarbonsäure

Cited by 63 publications

References 9 publications

Biobased polyesters and other polymers from 2,5-furandicarboxylic acid: a tribute to furan excellency

Biobased polyesters and other polymers from 2,5-furandicarboxylic acid: a tribute to furan excellency

Solid‐state polymerization and characterization of a copolyamide based on adipic acid, 1,4‐butanediamine, and 2,5‐furandicarboxylic acid

Polyesters, Polycarbonates and Polyamides Based on Renewable Resources

Contact Info

Product

Resources

About