Synthese et proprietes electrochimiques de sels conducteurs derives du tetramethyltetraselenofulvalene—I. Chlorure et bromure

Abstract. The use of various electrochemical techniquesin the synthesis, characterization and applications of molecularconductors derived from transition metal complexes of the dmit!" ligand, is reviewed (Hydmit = 4,5-dimercapto-I,3-dithia-2-thione). Cyclic voitammetry can be used for the detection of the formation of conductive species derived from the concerned complexes. The use of the TTF[Ni(dmithh compound! as electrode materialand its electrochemical behaviour with various supportingelectrolytes, is extensively studied. INTRODUCfIONMolecular metals have been the subject of extensive investigations over the last 20 years. The interest for such compounds has been recently raised again by the discovery ofelectrically superconductive molecular systems derived from TMTSF

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Use of Electrochemical Techniques in the Synthesis, Characterization and Application of Molecular Conductors: Cation Effects in the Oxidation and Reduction of TTF[Ni(dmit)₂]₂ Electrodes

Valade

Legros

Montauzon

et al. 1986

Israel Journal of Chemistry

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Synthese et proprietes electrochimiques de sels conducteurs derives du tetramethyltetraselenofulvalene–II. perchlorate, tetrafluoroborate, hexafluorophosphate

Lamache

Wuryanto

Benhamou

1985

Electrochimica Acta

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Synthese et proprietes electrochimiques de sels conducteurs derives du tetramethyltetraselenofulvalene—I. Chlorure et bromure

Cited by 2 publications

References 11 publications

Use of Electrochemical Techniques in the Synthesis, Characterization and Application of Molecular Conductors: Cation Effects in the Oxidation and Reduction of TTF[Ni(dmit)₂]₂ Electrodes

Use of Electrochemical Techniques in the Synthesis, Characterization and Application of Molecular Conductors: Cation Effects in the Oxidation and Reduction of TTF[Ni(dmit)₂]₂ Electrodes

Synthese et proprietes electrochimiques de sels conducteurs derives du tetramethyltetraselenofulvalene–II. perchlorate, tetrafluoroborate, hexafluorophosphate

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Synthese et proprietes electrochimiques de sels conducteurs derives du tetramethyltetraselenofulvalene—I. Chlorure et bromure

Cited by 2 publications

References 11 publications

Use of Electrochemical Techniques in the Synthesis, Characterization and Application of Molecular Conductors: Cation Effects in the Oxidation and Reduction of TTF[Ni(dmit)2]2 Electrodes

Use of Electrochemical Techniques in the Synthesis, Characterization and Application of Molecular Conductors: Cation Effects in the Oxidation and Reduction of TTF[Ni(dmit)2]2 Electrodes

Synthese et proprietes electrochimiques de sels conducteurs derives du tetramethyltetraselenofulvalene–II. perchlorate, tetrafluoroborate, hexafluorophosphate

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Use of Electrochemical Techniques in the Synthesis, Characterization and Application of Molecular Conductors: Cation Effects in the Oxidation and Reduction of TTF[Ni(dmit)₂]₂ Electrodes

Use of Electrochemical Techniques in the Synthesis, Characterization and Application of Molecular Conductors: Cation Effects in the Oxidation and Reduction of TTF[Ni(dmit)₂]₂ Electrodes