Synergy of garlic extract and deep eutectic solvents as promising natural Antibiotics: Experimental and COSMO-RS

Greener chemistry in analytical sciences: from green solvents to applications in complex matrices. Current challenges and future perspectives: a critical review

“…Depending on the (NA)DES and the solute, the solubility is based on their intermolecular interactions, which include not only hydrogen bonding, but also van der Waals, ion-dipole, or electrostatic interactions. 119,[129][130][131] The observed very good extractability of phytochemicals with NADESs is consistent with the hypothesis that NADESs form a natural environment in plant cells. 109 It should also be emphasized that hydrophilic and hydrophobic (NA)DESs containing at least one hydrophilic component (quasi-hydrophobic DES) are easily decomposed in water, which limits their use.…”

“…Extracts or solutions of certain compounds with a (NA)DES as solvent may act additively or even synergistically as antibacterial, cytotoxic, or antioxidant agents, which may be desirable or undesirable depending on the individual case. 119,120 In this regard, several studies confirmed stronger effects of DESs when compared to their individual constituents. 121,122 Organic acids as HBD constituents have been highlighted in experimental and computational studies as a major contributor to DES toxicity.…”

“…Depending on the (NA)DES and the solute, the solubility is based on their intermolecular interactions, which include not only hydrogen bonding, but also van der Waals, ion–dipole, or electrostatic interactions. 119,129–131…”

Novel hybrid QSPR-GPR approach for modeling of carbon dioxide capture using deep eutectic solvents

“…This approach, widely accepted and applied in the scientic literature, provides a standard method for dening the S s-prole of DESs. [104][105][106][107][108] By incorporating the contributions of each constituent in a weighted manner, the resulting S s-prole offers insights into the DES system's collective charge distribution and solvation behaviour. 54 The equation is formulated in the following manner:…”

3,4-Dimethoxy phenyl thiosemicarbazone as an effective corrosion inhibitor of copper under acidic solution: comprehensive experimental, characterization and theoretical investigations

“…The visual depiction illustrates the following: regions designated as hydrogen bond acceptors (HBA) are colored red, while non-polar areas are represented by green; hydrogen bond donor sites (HBD) are represented by blue. [89][90][91][92] The s-prole, as used in COSMO-RS analysis, represents a probability distribution of surface area vs. charge density. [93][94][95] Graphically depicted, the s-prole is commonly divided into three discrete regions:…”