Synergistic Organo‐Organocatalysis

Enantioselective merged gold/organocatalysis

“…4 The foundation for dual catalysis has been laid based on the utilization of two catalysts in one-pot, working in synchronization to enable a single synthetic transformation. In this regard, several dual catalytic systems merging metal–metal, 5 organo–organo 6 and metal–organocatalysts 7 have been devised to achieve unique molecular scaffolds with excellent levels of chemo-, regio- and stereoselectivity. Among these merged catalytic systems, the strategy involving the combination of transition metals and chiral organocatalysts has been enormously applied in the realm of asymmetric organic synthesis.…”