“…As shown in Fig. 3(a), the XPS spectra of O 1s were divided into three sections, where the first peak with binding energies ranging from 529.6 to 530.0 eV is ascribed to lattice oxygen (O Latt ); 32,33 the second section in the 531.3–531.7 eV range is attributed to oxygen contained in defective sites, which is so-called adsorbed oxygen (O Ads ); 34,35 and the minimum peak of the O 1s spectra centered at 533.0 eV could be identified as surface absorbed O 2 or H 2 O. 36,37 The binding energy of lattice oxygen for Cr 2 O 3 -P is lower than that of the other three catalysts.…”
“…As shown in Fig. 3(a), the XPS spectra of O 1s were divided into three sections, where the first peak with binding energies ranging from 529.6 to 530.0 eV is ascribed to lattice oxygen (O Latt ); 32,33 the second section in the 531.3–531.7 eV range is attributed to oxygen contained in defective sites, which is so-called adsorbed oxygen (O Ads ); 34,35 and the minimum peak of the O 1s spectra centered at 533.0 eV could be identified as surface absorbed O 2 or H 2 O. 36,37 The binding energy of lattice oxygen for Cr 2 O 3 -P is lower than that of the other three catalysts.…”
“…Steels, as critical metallic materials in civil engineering, are under scrutiny for corrosion protection through Ce-compounds via inhibition [182][183][184], CeCC deposition [185][186][187][188], and the utilization of Ce-compounds as active ingredients in protective coatings [183].…”
Section: Application Of Cerium Oxide and Soluble Salts-based Material...mentioning
Cerium oxide materials exhibit remarkable properties, positioning them as highly effective, environmentally friendly solutions across diverse applications. This chapter provides a comprehensive overview of fundamental concepts and technological methodologies related to cerium oxide (CeO2) and doped ceria-based materials. Emphasis is placed on electrochemical deposition, spray pyrolysis, and the sol-gel approach for synthesizing thin and thick layers of ceria. The versatility of these materials is explored, spanning from corrosion protection layers and specialized ceramic elements for sensor applications to components for solid oxide fuel cells (SOFCs) and electrodes for water-splitting cells. Additionally, the chapter delves into the promising applications of recently developed ceria-based nanomaterials in various fields, marking some advanced methods for CeO2-based materials synthesis. The key findings are succinctly summarized in the concluding section.
“…(l) POL curves for BS (bare steel), GL (galvanic layer), cerium conversion coatings deposited spontaneously (CeCC) and composite coatings consisting of double layers of GL and CeCC. [Reprinted with permission from ref . Copyright 2022, Elsevier].…”
Section: Applications and Prospects Of Ln Elementsmentioning
confidence: 99%
“…Increasing the immersion time to 1800 s tremendously increased the size of the pits along with the increment in the number of pits, produced from highly strong interaction of corrosive ions. Further the incorporation of cerium-based coatings on a steel substrate also proved to be anticorrosive in nature, where three types of coatings were tested as shown in Figure (l). In this study, before the deposition of cerium coatings by immersion in cerium solution (0.025 mol dm –3 of (NH 4 ) 2 Ce(NO 3 ) 5 and CeCl 3 ), Zn coatings had been deposited.…”
Section: Applications and Prospects Of Ln Elementsmentioning
Lanthanides (Ln), as an important class of materials, have recently generated global interest in modern technology due to their unique metallurgical, ceramic, catalytic, electronic, nuclear, and mechanical properties. Here,
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