2010
DOI: 10.1016/j.corsci.2010.07.034
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Synergistic effect of halide ions on improving corrosion inhibition behaviour of benzisothiozole-3-piperizine hydrochloride on mild steel in 0.5M H2SO4 medium

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Cited by 146 publications
(48 citation statements)
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“…In acid solutions, mild steel possesses positive charge at the corrosion potential. The chloride ions present in the solution get adsorbed on metal surface by creating an excess negative charge towards solution and it favors the adsorption of protonated inhibitor molecules on metal surface through electrostatic attraction [39,40]. Therefore the protonated RS molecules get adsorbed on mild steel surface by means of electrostatic interaction between chloride ions and inhibitor cations.…”
Section: Mechanism Of Inhibitionmentioning
confidence: 99%
“…In acid solutions, mild steel possesses positive charge at the corrosion potential. The chloride ions present in the solution get adsorbed on metal surface by creating an excess negative charge towards solution and it favors the adsorption of protonated inhibitor molecules on metal surface through electrostatic attraction [39,40]. Therefore the protonated RS molecules get adsorbed on mild steel surface by means of electrostatic interaction between chloride ions and inhibitor cations.…”
Section: Mechanism Of Inhibitionmentioning
confidence: 99%
“…Considering the chemical structures of the tested inhibitors in the present work, there are four types of adsorptions. Firstly, the metal surface becomes negatively charged by adsorbing sulfate anions (SO 4 --) on the surface (Pavithra, 2010). So, there are electrostatic interactions between negatively charged surface and positively charged atoms, which retard the anodic dissolution of iron (Aramaki et al, 1987).…”
Section: Mechanism Of Inhibitionmentioning
confidence: 99%
“…In this case, the shift in corr values is more than 85 mV, and analysis of the polarisation curves shows that the anodic current density is reduced significantly compared to the cathodic current density. Hence the polymer under investigation must be predominantly an anodic inhibitor inhibiting the anodic dissolution reaction [21,22].…”
Section: Pec-g-paammentioning
confidence: 99%