Synchronizing Deoxygenation and Hydrogenation to Effect Glycerol Hydrogenolysis over Pt/Nb2W15O50 at Low H2 Pressure
Jinghu Chen,
Hong Huang,
Hu Pan
et al.
Abstract:The
selective hydrogenolysis of glycerol to 1,3-propanediol
(1,3-PDO)
necessitates the precise tandem reactions of deoxygenation at a specific
location and the ensuing hydrogenation steps. Herein, a solid solution-supported
catalyst Pt/Nb2W15O50 was reported
for the hydrogenolysis of glycerol to 1,3-PDO. We engineered the exceptional
interaction between active Pt and oxygen vacancies to efficiently
integrate the deoxygenation and hydrogenation steps in tandem. The
strong interaction between active Pt and oxyge… Show more
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