The simultaneous determination of magnetoresistance and vectorial-resolved magnetization hysteresis curves in a spin valve structure reveals distinct magnetoresistive features for different magnetic field orientations, which are directly related to the magnetization reversal processes. Measurements performed in the whole angular range demonstrate that the magnetoresistive response originates from the intrinsic anisotropic angular dependence of the magnetization orientation between the two ferromagnetic layers. This also provides direct proof that the spin-dependent scattering in the bulk of the magnetic layers is at the origin of the magnetoresistive signal. Large magnetoresistance (MR) effects observed in ferromagnetic (FM) layers separated by nonmagnetic (NM) spacers have attracted sustained interest over the past decades for both fundamental and technological reasons. 1,2 The effects originate from spin-dependent scattering processes affecting electrons that travel across multilayered structures with different relative magnetization orientation between adjacent FM layers. 3 To observe large MR responses, one has to reorient the magnetization of the FM layers relative to one another, either by applying external magnetic fields (i.e., direct magnetic torque on the local magnetization) 1,5 or by injecting spin polarized currents (i.e., via transfer of angular momentum between the spin polarized conduction electrons and the local magnetization). 6,7 The maximum MR value is expected when the magnetic configuration of the FM layers reorients from a fully parallel (P) to a fully antiparallel (AP) configuration.Even though it is commonly assumed that the MR depends on the magnetic anisotropy of the multilayer structure, clear experimental proof of the direct relationship between the magnetoresistive behavior and the magnetization reversal processes, which determine the magnetic configuration of the FM layers, is still lacking. This is due to experimental limitations. Reported experiments rely on magnetization or MR hysteresis curves acquired independently 1-11 or in measurements performed at a fixed angle of the applied field, normally close to the easy axis (e.a.) direction, recording only the parallel component of the magnetization curve. As a consequence, widely different field-dependent magnetoresistive behaviors, including maximum MR values and curve shapes, are unexpectedly found for multilayers with similar structures.To tackle these limitations, we employ a magnetoresistanceoptical Kerr effect [M(R)-OKE] setup that allows us to determine simultaneously magnetoresistive responses and magnetization reversal processes. In this paper, we show that both amplitudes and shapes of the MR curves of a spin-valve structure, i.e., a magnetically free-FM layer, a NM spacing layer, and a pinned-FM layer, which is exchange-coupled to an antiferromagnetic (AFM) layer, 4 depend on the orientation of the applied magnetic field and are directly related to the magnetization reversal processes. The results directly show that the ...