Switchable Catalysis: Modular Synthesis of Functionalized Pyrimidinones via Selective Sulfide and Halide Cross‐Coupling Chemistry.

Abstract

Pyrimidine derivativesPyrimidine derivatives R 0510 Switchable Catalysis: Modular Synthesis of Functionalized Pyrimidinones via Selective Sulfide and Halide Cross-Coupling Chemistry. -The orthogonal selectivities of Suzuki and Stille cross-coupling reactions compared to the Liebeskind-Srogl procedure are demonstrated. -(KUSTURIN, C.; LIEBESKIND*, L. S.; RAHMAN, H.; SAMPLE, K.; SCHWEITZER, B.; SROGL, J.; NEUMANN, W. L.; Org. Lett. 5 (2003) 23, 4349-4352; St. Louis Lab., Pfizer Global Res. Dev., St. Louis, MO 63167, USA; Eng.) -Nuesgen 13-119