Sustainable Production of Carboxymethyl Cellulose: A Biopolymer Alternative from Sugarcane (Saccharum officinarum L.) Leaves
Teerapong Churam,
Phairat Usubharatana,
Harnpon Phungrassami
Abstract:This study explores the potential of sugarcane (Saccharum officinarum L.) leaves (SCLs), a significant agricultural waste, for the sustainable production of carboxymethyl cellulose (CMC) utilizing an innovative approach of carboxymethylation with monochloroacetic acid and varying sodium hydroxide (NaOH) concentrations (ranging from 20 to 60 g/100 mL). The optimal carboxymethylation condition was identified as 40 g/100 mL NaOH, which yielded the highest degree of substitution (DS = 0.86). Furthermore, a higher … Show more
“…Cellulose and its derivatives are sustainable biomaterials obtained from renewable resources that find applications as thickeners in various substances and fields, including food, tissue [2], cosmetics, pharmaceuticals, paints, and coatings [3]. Of particular interest is the conversion of cellulose into valuable cellulose esters and ethers like ethyl cellulose, methyl cellulose, and hydroxyethyl cellulose, which has gained significant interest in the field of green and sustainable chemistry, resulting in advancements in environmental protection technologies [4]. Additionally, these materials demonstrate characteristics including increased strength and durability in composites, biodegradability [5], non-toxicity [6], and a relatively low cost [7].…”
In the context of the ongoing evolution of the global economy and increasing environmental awareness, green sustainable development has emerged as a crucial pathway for future advancements in the lubrication industry. In this study, we prepared bio-based greases by employing a thickener system consisting of polyhydroxyalkanoate (P34HB) and ethyl cellulose, with castor oil serving as a base oil. The results indicate that ethyl cellulose significantly and effectively enhances the grease system’s mechanical and colloidal stability. Notably, the addition of 5 wt% ethyl cellulose leads to superior mechanical and colloidal stability, while increasing concentrations gradually result in rheological properties similar to those of oleogels. Furthermore, the wear volume of grease containing 5 wt% ethyl cellulose was reduced by 39.20% compared to that of a reference P34HB grease, demonstrating its exceptional wear resistance. The present study provides a theoretical foundation and empirical evidence for the future development of biodegradable greases as substitutes for non-degradable materials, thereby expanding the range of environmentally friendly greases formulated with biomass-based thickeners.
“…Cellulose and its derivatives are sustainable biomaterials obtained from renewable resources that find applications as thickeners in various substances and fields, including food, tissue [2], cosmetics, pharmaceuticals, paints, and coatings [3]. Of particular interest is the conversion of cellulose into valuable cellulose esters and ethers like ethyl cellulose, methyl cellulose, and hydroxyethyl cellulose, which has gained significant interest in the field of green and sustainable chemistry, resulting in advancements in environmental protection technologies [4]. Additionally, these materials demonstrate characteristics including increased strength and durability in composites, biodegradability [5], non-toxicity [6], and a relatively low cost [7].…”
In the context of the ongoing evolution of the global economy and increasing environmental awareness, green sustainable development has emerged as a crucial pathway for future advancements in the lubrication industry. In this study, we prepared bio-based greases by employing a thickener system consisting of polyhydroxyalkanoate (P34HB) and ethyl cellulose, with castor oil serving as a base oil. The results indicate that ethyl cellulose significantly and effectively enhances the grease system’s mechanical and colloidal stability. Notably, the addition of 5 wt% ethyl cellulose leads to superior mechanical and colloidal stability, while increasing concentrations gradually result in rheological properties similar to those of oleogels. Furthermore, the wear volume of grease containing 5 wt% ethyl cellulose was reduced by 39.20% compared to that of a reference P34HB grease, demonstrating its exceptional wear resistance. The present study provides a theoretical foundation and empirical evidence for the future development of biodegradable greases as substitutes for non-degradable materials, thereby expanding the range of environmentally friendly greases formulated with biomass-based thickeners.
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