Sustainable Potassium-Ion Battery Anodes Derived from Waste-Tire Rubber

Li, Yunchao; Adams, Ryan A.; Arora, Anjela; Pol, Vilas G.; Levine, Alan M.; Lee, Richard J.; Akato, Kokouvi; Naskar, Amit K.; Paranthaman, Mariappan Parans

doi:10.1149/2.1391706jes

Cited by 94 publications

(49 citation statements)

References 33 publications

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“…Alloying of alkali metals with other elements has been regarded as a potential route to prepare high-capacity anodes for Li [55,56] Jiang and co-workers [37] Hard carbon microspheres Cohn et al [53] Graphite Carbon black + PVDF 1 m KPF 6 Xing et al [46] Poly nanocrystalline graphite Li et al [45] Tire-derived carbon Ma et al [51] P Chen et al [43] N-rich hard carbon 10% PVDF 0.8 m KPF 6 in EC:DEC -250 -180 mA h g −1 (4000 cycles at 1.8 C)…”

Section: Alloying Anodesmentioning

confidence: 99%

Recent Progress and Perspective in Electrode Materials for K‐Ion Batteries

Kim

Bianchini

et al. 2017

Advanced Energy Materials

601

465

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and demand in terms of time and space. Thus, grid-level stationary energy storage systems (ESSs) play a key role in making renewable energies both effective and efficient and thereby shaping a more sustainable and environmental friendly society.Although different energy storage technologies including mechanical, electrical, chemical, and electrochemical systems have been proposed, [2,3] mechanical energy storage through pumped hydroelectricity currently dominates the market (≈95% of the installed capacity, ≈183 GW). [4] Electrochemical energy storage is also being considered as a promising option for ESSs based on its flexibility of deployment with little restriction on size and geographical location, low maintenance costs, large energy density, high round-trip efficiency, and long cycle life. [3,5,6] The market for Li-ion batteries (LIBs), originally commercialized for portable electronic devices (i.e., cell phones and laptops), is now expanding to electric vehicles (EVs) and gridlevel ESSs. However, it remains debatable whether the global Li reserves, ≈14 million tons, can meet the increasing demand for such large-scale applications. [7][8][9] The price of lithium carbonate, which is a primary precursor for LIBs, has been continuously increasing since 2000, [10] and this trend is likely to accelerate once the EV and ESS markets take off. Moreover, Li is geographically limited to specific regions: ≈86% of the Li reserves are located in Bolivia, Chile, China, Argentina, and Australia; [9] therefore, geopolitical issues may arise. A more pressing issue for Li-ion markets is the use of Co in all high-energy-density systems. With more than 50% of all mined Co destined for use in Li-ion technology, and a substantial fraction of that coming from the Democratic Republic of the Congo, Li-ion growth may be hampered by the availability of Co. [11] As a less expensive alternative to LIBs, Na-ion batteries (NIBs) have been extensively studied. [6,[12][13][14] The relatively high standard redox potential of Na/Na + leads to a lower working voltage and thereby lower energy density than Li-ion. In addition, hard carbon, which is associated with a high production cost and low material's density, must be used as an anode in NIBs, as graphite, which is the standard anode for LIBs, cannot store Na ions. [15][16][17] Recently, K-ion batteries (KIBs) have emerged as another possible energy storage system. [18][19][20] It is notable that the abundance of K resources in the Earth's crust and oceans is similar to that of Na (Figure 1a). [21,22] The cost of potassium carbonate The development of rechargeable batteries using K ions as charge carriers has recently attracted considerable attention in the search for cost-effective and large-scale energy storage systems. In light of this trend, various materials for positive and negative electrodes are proposed and evaluated for application in K-ion batteries. Here, a comprehensive review of ongoing materials research on nonaqueous K-ion batteries is offered. Information on the status of ...

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Section: Alloying Anodesmentioning

confidence: 99%

Recent Progress and Perspective in Electrode Materials for K‐Ion Batteries

Kim

Bianchini

et al. 2017

Advanced Energy Materials

601

465

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“…Hexacyanometalates, known as Prussian blue analogues, can be described with a general formula of A x M[Fe(CN) 6 ] y ∙ zH 2 O (A stands for alkali ions, M represents transition metals, 0 < x < 2) . Prussian blue analogues generally have face‐centered cubic (FCC) structures within the Fm3m space group.…”

Section: Cathode Materialsmentioning

confidence: 99%

Review on Recent Advances of Cathode Materials for Potassium‐ion Batteries

Sha

Liu

Zhao

et al. 2020

Energy & Environ Materials

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Potassium‐ion batteries (PIBs) as a promising supplement to lithium‐ion batteries have drawn great attention attributing to the abundant potassium resources, the fast‐ionic conductivity of potassium ions in electrolyte, and the low standard redox potential of potassium. However, the development of PIBs is still in its infancy, which is largely restricted by the fact that the electrode materials, especially the cathode materials of PIBs, are far from satisfactory in practical applications regarding the capacity, voltage, and cycle life. Therefore, most of current research efforts have been devoted to exploring new and high‐performance electrode materials for achieving PIBs with high capacity and voltage as well as excellent cyclability. In this review, the recent advancements on cathode materials for PIBs are specially summarized. Besides, technological developments, scientific challenges, and future research opportunities of cathode materials for PIBs are also briefly outlooked.

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“…Thus, an appropriate host material is required to develop a fully functional cell. Recently, a study demonstrated the utilization of waste‐tires to produce anode materials for KIBs . The tire‐derived hard carbon anode could deliver a capacity of 155 mAh g −1 at C/2 after 200 cycles .…”

Section: Anode Materialsmentioning

confidence: 99%

Advancements and Challenges in Potassium Ion Batteries: A Comprehensive Review

Rajagopalan

Tang

et al. 2020

Adv Funct Materials

663

401

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Demand for energy in day to day life is increasing exponentially. However, existing energy storage technologies like lithium ion batteries cannot stand alone to fulfill future needs. In this regard, potassium ion batteries (KIBs) that utilize K ions in their charge storage mechanism have attracted considerable attention due to their unique properties and are therefore established as one of the future battery systems of interest among the scientific community. Nevertheless, the development and identification of appropriate electrode materials is very essential for practical applications. This review features the current development in KIBs electrode and electrolyte materials, the present challenges facing this technology (in the commercial aspect), and future aspects to develop fully functional KIBs. The potassium storage mechanisms, evolution of the KIBs, and the advantages and disadvantages of each category of materials are included. Additionally, various approaches to enhance the electrochemical performances of KIBs are also discussed. This review is not only an amalgamation of different viewpoints in literature, but also contains concise perspectives and strategies. Moreover, the potential emergence of a novel class of K‐based dual ion batteries is also analyzed for the first time.

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Sustainable Potassium-Ion Battery Anodes Derived from Waste-Tire Rubber

Cited by 94 publications

References 33 publications

Recent Progress and Perspective in Electrode Materials for K‐Ion Batteries

Recent Progress and Perspective in Electrode Materials for K‐Ion Batteries

Review on Recent Advances of Cathode Materials for Potassium‐ion Batteries

Advancements and Challenges in Potassium Ion Batteries: A Comprehensive Review

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