The distribution of surface and ground waters in Northern Ireland were mapped with respect to p H and total hardness and the distributions discussed in relation to the regional geology and pedology. These waters were grouped into 3 categories depending on their vulnerability to acidification. Three upland areas, the Mournes, the western Spcrrins and the northern Glens of Antrim, were identified as being vulnerable to acidification. Concentrations of total and labile aluminium in these areas were high and, in the Mournes and Sperrin areas, exceeded the EC directive on total aluminium in drinking water. However, because of their differing geology and pedology, only the Blournes area had labile aluminium levels which gave cause for concern. A fish survey in a reservoir in the Mourncs catchment showed that it supported a small but self-sustaining population of brown trout (Salmo trutta) which, although small in size, showed no signs of deformity.