Cadwell Creek in west central Massachusetts, like many New England watersheds, is underlain by crystalline metamorphic bedrock with glacial till serving as the main unconfined aquifer. Groundwater hydrology and chemistry were monitored in a network of 10 wells. Low air‐equilibrated pH (lpar;4.7–5.4), low alkalinity (near 0 mg L−1 CaCO3), and low conductivity (23–34 μmhos) occur in the groundwater in the downstream parts of the watershed where hydraulic gradients are steep and groundwater residence times are short (about 3 months). On the other hand, the headwater areas are typified by low hydraulic gradients and slower groundwater velocities, with correspondingly higher air‐equilibrated groundwater pH (7.0–7.4), alkalinity up to 26 mg L−1, and higher conductivity (32–71 μmhos). Therefore even in this supposedly acid‐sensitive terrain, groundwater is neutralized if mineral‐water contact time is sufficiently long (here ∼1 year). Because some 70% of Cadwell Creek base flow originates as shallow groundwater in the lower reaches of the watershed, the stream is very acidic most of the year. Only during late summer, when deeper base flow from headwater sources prevails, does the pH and alkalinity of the streamwater rise appreciably.