Surfactant-thermal method to prepare two novel two-dimensional Mn–Sb–S compounds for photocatalytic applications

Nie, Lina; Xiong, Wei‐Wei; Li, Pei‐Zhou; Han, Jianyu; Zhang, Guodong; Yin, Shou-Wei; Zhao, Yanli; Xu, Rong; Zhang, Qichun

doi:10.1016/j.jssc.2014.08.018

Cited by 30 publications

(23 citation statements)

References 43 publications

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“…[57] Thes urfactant PEG-400 was crucial to the formation of these compounds, since no crystal could be obtained without the addition of PEG-400. [58] Photocatalytic investigations indicated that both compounds display hydrogen-evolution behavior under visible-light irradiation. [58] Photocatalytic investigations indicated that both compounds display hydrogen-evolution behavior under visible-light irradiation.…”

Section: Methodsmentioning

confidence: 99%

Surfactants as Promising Media for the Preparation of Crystalline Inorganic Materials

2015

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Given that surfactants can control the shape and size of micro-/nanoparticles, they should be able to direct the growth of bulk crystals. This Minireview summarizes recent developments in the application of surfactants for the preparation of new crystalline inorganic materials, including chalcogenides, metal-organic frameworks, and zeolite analogues. The roles of surfactants in different reaction systems are discussed.

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Section: Methodsmentioning

confidence: 99%

Surfactants as Promising Media for the Preparation of Crystalline Inorganic Materials

2015

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“…With the rising number of thioantimonates and antimony sulfide compounds, the possibilities regarding their applications increased significantly. It was shown that such compounds exhibited promising properties in photocatalytic hydrogen evolution reaction, [1][2][3] photocatalytic dye degradation, [4,5] or as anode materials for lithium ion batteries. [6] Due to the flexible coordination geometries of Sb(III), Sb-S bond lengths and S-Sb-S angles, a large variety of thioantimonate(III) structures ranging from discrete anions up to threedimensional networks have been synthesized and characterized.…”

Section: Introductionmentioning

confidence: 99%

“…In comparison to the properties of divalent late transition metal cations, the Mn 2+ ion behaves quite different, as it shows a similar affinity to N donor atoms and S 2anions, and thus is readily integrated into a variety of thioantimonate networks. [3,10,12,17,18,[20][21][22][23][24][25][26][27]28] Recently, we reported the synthesis of new thioantimonates using TM 2+ complexes and Schlippe's salt, Na 3 SbS 4 •9H 2 O, as a water-soluble precursor. [29] This reaction system is characterized by a short reaction time for product formation and a remarkable robustness against changes of the reaction parameters.…”

Section: Introductionmentioning

confidence: 99%

[Mn(terpy)Sb₂S₄]_n, a 1D Network of MnSb₄S₅ Rings Exhibiting a Pronounced Magnetocaloric Effect and Luminescence

et al. 2020

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The solvothermal reaction of an aqueous solution of Na 3 SbS 3 or Schlippe's Salt (Na 3 SbS 4 ·9H 2 O) in the presence of Mn(ClO 4 ) 2 ·6H 2 O and terpy (terpy = 2,2′:6′,2′′-terpyridine) or the [Mn(terpy)] 2+ complex led to crystallization of the new compound [Mn(terpy)Sb 2 S 4 ] n (I). The unique crystal structure of I features chains formed by fused MnSb 4 S 5 rings. The Mn 2+ cation is coordinated by one terpy ligand and two S 2anions resulting in a distorted MnN 3 S 2 trigonal bipyramid. The terpy ligands point to the exterior of the chains, distances between [a] F.Luminescence measurements: The emission and excitation spectra were recorded at room temperature in quartz ampoules, using a FL3-22 Fluorolog-3 fluorescence spectrometer (HORIBA Jobin Yvon GmbH, Unterhaching, Germany), equipped with a R928P Photomultiplier and a 450 W xenon lamp.

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“…Therefore, hydrazine can be employed to simultaneously serve as reaction medium and structure‐directing agent for synthesizing novel chalcogenides. Although hydrazine has been successfully applied to control the formation of binary or ternary chalcogenides, the use of hydrazine for synthesizing inorganic quaternary chalcogenides has only recently been developed by our group . Such successful preparation inspired us to extend this strategy, and two new quaternary thioarsenates(III), SrAg 4 As 2 S 6 ⋅2 H 2 O ( 1 ) and BaAgAsS 3 ( 2 ), were obtained through the hydrazine‐hydrothermal method.…”

Section: Introductionmentioning

confidence: 99%

Facile Hydrazine‐Hydrothermal Syntheses and Characterizations of Two Quaternary Thioarsenates(III): Two‐Dimensional SrAg₄As₂S₆⋅2 H₂O and One‐Dimensional BaAgAsS₃

Yan

Liu

Chai

et al. 2016

Chemistry An Asian Journal

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Two new quaternary thioarsenates(III), SrAg4 As2 S6 ⋅2 H2 O (1) and BaAgAsS3 (2), have been prepared through a hydrazine-hydrothermal method at low temperature. Compound 1 possesses a two-dimensional (2D) layer network, while compound 2 features a one-dimensional (1D) column structure. The detailed structure analysis indicates that Sr(2+) and Ba(2+) cations have different directing effects on the structures of thioarsenates(III). Both experimental and theoretical studies demonstrate that compounds 1 and 2 are narrow-gap semiconductors. Our success in synthesizing these two quaternary thioarsenates(III) proves that the hydrazine-hydrothermal technique is a powerful yet facile synthetic method for exploring new complex chalcogenides with diverse crystal structures and interesting physical properties.

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Surfactant-thermal method to prepare two novel two-dimensional Mn–Sb–S compounds for photocatalytic applications

Cited by 30 publications

References 43 publications

Surfactants as Promising Media for the Preparation of Crystalline Inorganic Materials

Surfactants as Promising Media for the Preparation of Crystalline Inorganic Materials

[Mn(terpy)Sb₂S₄]_n, a 1D Network of MnSb₄S₅ Rings Exhibiting a Pronounced Magnetocaloric Effect and Luminescence

Facile Hydrazine‐Hydrothermal Syntheses and Characterizations of Two Quaternary Thioarsenates(III): Two‐Dimensional SrAg₄As₂S₆⋅2 H₂O and One‐Dimensional BaAgAsS₃

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Surfactant-thermal method to prepare two novel two-dimensional Mn–Sb–S compounds for photocatalytic applications

Cited by 30 publications

References 43 publications

Surfactants as Promising Media for the Preparation of Crystalline Inorganic Materials

Surfactants as Promising Media for the Preparation of Crystalline Inorganic Materials

[Mn(terpy)Sb2S4]n, a 1D Network of MnSb4S5 Rings Exhibiting a Pronounced Magnetocaloric Effect and Luminescence

Facile Hydrazine‐Hydrothermal Syntheses and Characterizations of Two Quaternary Thioarsenates(III): Two‐Dimensional SrAg4As2S6⋅2 H2O and One‐Dimensional BaAgAsS3

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[Mn(terpy)Sb₂S₄]_n, a 1D Network of MnSb₄S₅ Rings Exhibiting a Pronounced Magnetocaloric Effect and Luminescence

Facile Hydrazine‐Hydrothermal Syntheses and Characterizations of Two Quaternary Thioarsenates(III): Two‐Dimensional SrAg₄As₂S₆⋅2 H₂O and One‐Dimensional BaAgAsS₃